BIS(TRICYCLOHEXYLPHOSPHINE)[(PHENYLTHIO)METHYLENE]RUTHENIUM (IV) DICHLORIDE

CAS No.：219770-99-7

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BIS(TRICYCLOHEXYLPHOSPHINE)[(PHENYLTHIO)METHYLENE]RUTHENIUM (IV) DICHLORIDE Basic information

Reactions

Product Name:	BIS(TRICYCLOHEXYLPHOSPHINE)[(PHENYLTHIO)METHYLENE]RUTHENIUM (IV) DICHLORIDE
Synonyms:	Bis(tricyclohexylphosphine)[(phenylthio)methylene]ruthenium(II)dichloride,min.97%;Bis(tricyclohexylphosphine)[(phenylthio)Methylene]rutheniuM (II) dichloride,97%;Bis(tricyclohexylphosphine)[(phenylthio)methylene]ruthenium(II) dichloride, min. 97%;Bis(tricyclohexylphosphine)[(phenylthio)methylene]ruthenium(IV) dichloride,97%;Dichloro[(phenylthio)methylene]bis(tricyclohexylphosphine)ruthenium;Bis(tricyclohexylphosphine)[(phenylthio)methylene]ruthenium (II) dichloride;BIS(TRICYCLOHEXYLPHOSPHINE)[(PHENYLTHIO)METHYLENE]RUTHENIUM (IV) DICHLORIDE;Bis(tricyclohexylphosphine)[(phenylthio)methylene]ruthenium(II)
CAS:	219770-99-7
MF:	C43H72Cl2P2RuS
MW:	855.02
EINECS:
Product Categories:	metal-phosphine complexes;Ru
Mol File:	219770-99-7.mol

BIS(TRICYCLOHEXYLPHOSPHINE)[(PHENYLTHIO)METHYLENE]RUTHENIUM (IV) DICHLORIDE Chemical Properties

form	Powder
color	purple
EPA Substance Registry System	Ruthenium, dichloro[(phenylthio)methylene]bis(tricyclohexylphosphine)- (219770-99-7)

Safety Information

Risk Statements	36/37/38
Safety Statements	26-36/37/39

MSDS Information

BIS(TRICYCLOHEXYLPHOSPHINE)[(PHENYLTHIO)METHYLENE]RUTHENIUM (IV) DICHLORIDE Usage And Synthesis

Reactions

Metathesis catalyst, stable in air and can be used in aqueous media.
Catalyst of choice for the ring-opening metathesis polymerization of cycloolefins.
Catalyst concentration 2-3 times lower than comparable phenyl and vinyl substituted ruthenium carbenes.
Excellent initiator for solvent-free polymerization and control of initiation rates and gelation times.
Highly selective catalyst for the ring opening/cross-metathesis of norbornene derivatives.

BIS(TRICYCLOHEXYLPHOSPHINE)[(PHENYLTHIO)METHYLENE]RUTHENIUM (IV) DICHLORIDE Preparation Products And Raw materials

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