Dess-Martin periodinane

Dess-Martin periodinane
  • CAS No.:87413-09-0
Other grades of this product :

Melting point 130-133 °C (lit.)
Boiling point 40 °C
density 1.369 g/mL at 25 °C
Fp >221 °F
storage temp. -20°C
solubility Soluble in chloroform, acetone, acetonitrile and methylene chloride. Slightly soluble in ether and hexane.
form Liquid
color Colorless to light yellow
Sensitive Light Sensitive
Merck 14,2933
BRN 4548207
InChIKeyNKLCNNUWBJBICK-UHFFFAOYSA-N
CAS DataBase Reference87413-09-0(CAS DataBase Reference)

It is one of the most widely used, mild and highly selective oxidants in modern organic synthesis. It is mainly used to oxidize primary alcohols to corresponding aldehydes and secondary alcohols to ketones. The oxidation reaction conditions of DMP to alcohol are very mild, generally feeding at low temperature and reacting at room temperature. Most reactions complete within minutes to hours, and yields are normally maintained at relatively high or very high levels. Its advantages are mild reaction conditions, moderate speed, less dosage and simple post-processing.

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