(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY

CAS No.：656233-53-3

Other grades of this product :

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY Basic information

Reaction

Product Name:	(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY
Synonyms:	(R)-SHIP;(S)-SHIP;PHENYL-[(R)-1,1-SPIROBIINDANE-7,7-DIYL]-PHOSPHITE;PHENYL-[(S)-1,1-SPIROBIINDANE-7,7-DIYL]-PHOSPHITE;(11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-phenoxy,min.98%(R)-ShiP;Phenyl-[(R)-1,1-spirobiindane-7,7-diyl]-phosphite, (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1μ,7μ-fg][1,3,2]dioxaphosphocin-5-phenoxy;(11AS)-(-)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY;(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY
CAS:	656233-53-3
MF:	C23H19O3P
MW:	374.37
EINECS:
Product Categories:
Mol File:	656233-53-3.mol

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY Chemical Properties

Melting point	104-106°C
alpha	+216° (c 0.5, CH2Cl2)
form	solid
color	white
Sensitive	moisture sensitive

Safety Information

Hazard Codes	Xn
Risk Statements	22

MSDS Information

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY Usage And Synthesis

Reaction

Chiral ligands for rhodium-catalyzed arylation of aldehydes with arylboronic acids.
Chiral ligands for rhodium-catalyzed arylation of imines with arylboronic acids.
Chiral ligands for rhodium-catalyzed arylation of α-ketoesters with arylboronic acids.
Chiral ligands for palladium-catalyzed asymmetric umpolung allylation of aldehydes.
Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of (Z)-β-arylenamides.

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY Preparation Products And Raw materials

Raw materials

Ethanol-->Sodium hydroxide-->Hydrochloric acid-->Ethyl acetate-->Tetrahydrofuran-->Dichloromethane-->PETROLEUM ETHER-->Toluene-->Triethylamine-->Acetone-->Sodium bicarbonate-->Hydrogen peroxide-->Palladium-->Hydrogen-->Phosphorus trichloride-->Nickel-->Phenol-->Benzyl chloride-->N,N-Diisopropylethylamine-->Sodium bromide-->Methanesulfonic acid-->(S)-1,1'-SPIROBIINDANE-7,7'-DIOL-->Boron tribromide-->3-Hydroxybenzaldehyde-->(R)-1,1'-SPIROBIINDANE-7,7'-DIOL-->Cinchonidine-->CALCIUM HYDRIDE

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