4-NITROBENZO-18-CROWN-6

4-NITROBENZO-18-CROWN-6
  • CAS No.:53408-96-1
Other grades of this product :
4-NITROBENZO-18-CROWN-6 Basic information
Product Name:4-NITROBENZO-18-CROWN-6
Synonyms:4'-NITROBENZO-18-CROWN-6;4-NITROBENZO-18-CROWN-6;4'-NITROBENZO-18-CROWN 6-ETHER;2,3-(4-NITROBENZO)-1,4,7,10,13,16-HEXAOXACYCLOOCTADEC-2-ENE;NITROBENZO-18-CROWN-6;4-Nitrobenzo-18-crown-6,99%;NITROBENZO-18-CROWN-6, 99+%;1,16-(4-Nitro-1,2-phenylene)-1,4,7,10,13,16-hexaoxahexadecane
CAS:53408-96-1
MF:C16H23NO8
MW:357.36
EINECS:
Product Categories:Crown Ethers;Functional Materials;Macrocycles for Host-Guest Chemistry;Chelation/Complexation Compounds;Crown Ethers;Synthetic Reagents
Mol File:53408-96-1.mol
4-NITROBENZO-18-CROWN-6 Chemical Properties
Melting point 82-86 °C
Boiling point 453.11°C (rough estimate)
density 1.163
refractive index 1.5230 (estimate)
form powder to crystal
color White to Yellow
CAS DataBase Reference53408-96-1(CAS DataBase Reference)
Safety Information
Hazard Codes Xi,C,F
Risk Statements 36/37/38-34-11
Safety Statements 26-36-45-36/37/39-16
WGK Germany 3
3
HS Code 29329985
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
4-NITROBENZO-18-CROWN-6 Usage And Synthesis
Chemical PropertiesLIGHT YELLOW FLUFFY POWDER
Purification MethodsIf impure and discoloured, then chromatograph it through Al2O3 and elute with *C6H6/hexane (1:1) containing 1% MeOH. The fractions are followed by TLC on Al2O3 (with Dragendorff's reagent for detection: RF 0.6 in the above solvent system). Recrystallise the residues from the required fractions from *C6H6/hexane to give yellowish leaflets. It complexes with Na or K ions with logKNa 3.95 and logKK 4.71. [Petranek & Ryba Collect Chem Czech Chem Commun 39 2033 1974.]
4-NITROBENZO-18-CROWN-6 Preparation Products And Raw materials

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