TRANS-2-HEXEN-1-OL

TRANS-2-HEXEN-1-OL
  • CAS No.:2305-21-7
Other grades of this product :
TRANS-2-HEXEN-1-OL Basic information
Product Name:TRANS-2-HEXEN-1-OL
Synonyms:T2 HEXENOL;TRANS-2-HEXEN-1-YL ALCOHOL;TRANS-2-HEXENOL;TRANS-1-HYDROXY-2-HEXENE;FEMA 2562;HEX-2(TRANS)-EN-1-OL;HEXEN-1-OL,TRANS-2-;2-HEXENOL
CAS:2305-21-7
MF:C6H12O
MW:100.16
EINECS:218-972-1
Product Categories:
Mol File:2305-21-7.mol
TRANS-2-HEXEN-1-OL Chemical Properties
Melting point -46.6°C (estimate)
Boiling point 158-160 °C(lit.)
density 0.849 g/mL at 25 °C(lit.)
refractive index n20/D 1.438(lit.)
FEMA 2562 | 2-HEXEN-1-OL
Fp 130 °F
pka14.70±0.10(Predicted)
JECFA Number1354
EPA Substance Registry System2-Hexen-1-ol (2305-21-7)
Safety Information
Hazard Codes Xi
Risk Statements 10-36/37/38
Safety Statements 26-36
RIDADR UN 1987 3/PG 3
WGK Germany 2
RTECS MP8390000
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
TRANS-2-HEXEN-1-OL Usage And Synthesis
Description2-Hexen-l-ol has a powerful, fruity, green, wine-like, leafy odor and a sweet, fruity flavor important to strawberry and orange juice. The ds-form can be prepared by hydrogenation of ds-2-hexenol, using an aqueous suspension of colloidal palladium; from cis- 4-chloro-2-butenol and magnesium ethyl bromide; the commercial product is a mixture of the cis- and trans-isomers and can be prepared from propyl vinyl carbinol by heating with aluminum oxide.
Chemical Properties2-Hexen-1-ol has a powerful, fruity-green odor, with a sweet, fruity flavor important to strawberry and orange juice
OccurrenceReported found as a constituent of fresh raspberry aroma; also identified in Valencia orange juice and apple aroma, probably occurring as an ester. Also reported found in raw and cooked asparagus, cooked potato, cooked beef, hop oil, brandy, beer, white wine, roasted peanut, soybean, olive, prune, prickly pear, malt, kiwifruit, loquat, quince, apple, peach, strawberry, tamarind, tomato and tea
PreparationThe cis-form can be prepared by hydrogenation of cis-2-hexenol, using an aqueous suspension of colloidal palladium; from cis-4-chloro-2-butenol and magnesium ethyl bromide; the commercial product is a mixture of the cis- and trans-isomers and can be prepared from propyl vinyl carbinol by heating with aluminum oxide.
Aroma threshold valuesAroma characteristics at 1.0%: fresh, fatty green, tomato vegetative, with leafy, green fruity and herbal nuances.
Taste threshold valuesTaste characteristics at 5 ppm: fresh, leafy green, slightly fatty with grassy, fruity and juicy nuances, tomato and celery nuances.
TRANS-2-HEXEN-1-OL Preparation Products And Raw materials
Raw materialshex-2-enal-->TRANS-2-HEXENOIC ACID-->Hexanoic acid

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