Other grades of this product :
| 4-Nitrosophenol Basic information |
| 4-Nitrosophenol Chemical Properties |
| Melting point | 132-144°C | | Boiling point | 229.19°C (rough estimate) | | density | 1.3147 (rough estimate) | | vapor pressure | 0.003Pa at 20℃ | | refractive index | 1.5423 (estimate) | | solubility | soluble in Methanol | | form | powder to crystal | | pka | pK1:6.48 (25°C) | | color | Pale-yellow, orthorhombic needles | | Water Solubility | <0.1 g/100 mL at 21 ºC | | Merck | 14,6642 | | Stability: | Stability Flammable. Incompatible with strong oxidizing agents. Explodes when heated, or in contact with acids or alkalies. | | LogP | 1.1 at 20℃ | | CAS DataBase Reference | 104-91-6(CAS DataBase Reference) | | NIST Chemistry Reference | Phenol, 4-nitroso-(104-91-6) | | EPA Substance Registry System | p-Nitrosophenol (104-91-6) |
| 4-Nitrosophenol Usage And Synthesis |
| Chemical Properties | black solid | | Uses | Dyes. | | Hazard | Dangerous fire and explosion risk, reacts
violently with acids and alkalies, may explode spontaneously, intraplant transport must be in tightly
covered steel barrels. | | Safety Profile | Poison by parented
and intraperitoneal routes. Mutation data
reported. An irritant and sensitizer. Many
nitroso compounds are carcinogens. A very
dangerous fire and explosion hazard. When
exposed to heat or flame, it burns
explosively. Contamination by acid or alkali
may cause ignition . Can heat spontaneously
and cause fire. When heated to decomposition it emits toxic fumes of NOx.
See also NITROSO COMPOUNDS. | | Purification Methods | 4-Nitrosophenol forms yellow crystals from xylene, *C6H6 (m ~144o) or Et2O (m 128-129o, dec). [Beilstein 7 H 622, 7 II 574, 7 III 3367.] |
| 4-Nitrosophenol Preparation Products And Raw materials |
| Preparation Products | Sulphur Blue 7-->Sulphur Red 6-->Vat Blue 42-->Vat Blue 43-->1,4-Benzoquinone dioxime-->C.I.Leuco Sulphur Red 6-->Sulphur Red 6-->Sulphur Blue 7 -Leuco-->N-(2,4-diamino-5-(4-oxocyclohexa-2,5-dienylideneamino)phenyl)acetamide-->C.I. Sulphur Violet 5 (8CI)-->C.I. Sulphur Violet 4 (8CI)-->C.I. Sulphur Violet 3 (8CI)-->2,5-Cyclohexadien-1-one, 4-[[4-(phenylamino)phenyl]imino]-, reaction products with sodium sulfide (Na2(Sx))-->Acetamide, N-[2,4-diamino-5-[(4-oxo-2,5-cyclohexadien-1-ylidene)amino]phenyl]-, reaction products with sodium sulfide (Na2(Sx)), oxidized-->Sulfurized phenols-->C.I. Sulphur Blue 6 (8CI,9CI)-->Benzenesulfonic acid, 4-[[4-[(4-hydroxyphenyl)amino]phenyl]amino]-, reaction products with sodium sulfide (Na2(Sx)), leuco derivs.-->Leuco Sulphur Violet 3-->Leuco Sulphur Blue 2-->2,5-Cyclohexadien-1-one, 4-[[4-(phenylamino)phenyl]imino]-, reaction products with sodium sulfide (Na2(Sx)), leuco derivs. |
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