Product

(+)-CHLOROMETHYL MENTHYL ETHER

CAS No.：103128-76-3

Other grades of this product :

(+)-CHLOROMETHYL MENTHYL ETHER Basic information

Product Name:	(+)-CHLOROMETHYL MENTHYL ETHER
Synonyms:	(1R,2S,4S)-2-(CHLOROMETHYLOXY)-1-ISOPROPYL-4-METHYLCYCLOHEXANE;(+)-CHLOROMETHYL MENTHYL ETHER;(+)-Chloromethyl menthyl ether, 97% ee;Cyclohexane, 2-(chloromethoxy)-4-methyl-1-(1-methylethyl)-, (1R,2S,4S)-
CAS:	103128-76-3
MF:	C11H21ClO
MW:	204.74
EINECS:
Product Categories:	Chiral Building Blocks;Ethers;Organic Building Blocks
Mol File:	103128-76-3.mol

(+)-CHLOROMETHYL MENTHYL ETHER Chemical Properties

Boiling point	72 °C/0.4 mmHg (lit.)
density	0.994 g/mL at 25 °C (lit.)
refractive index	n20/D 1.467(lit.)
Fp	225 °F
storage temp.	-20°C
optical activity	[α]24/D +181.0°, c = 2 in methylene chloride
CAS DataBase Reference	103128-76-3

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-36
WGK Germany	3

MSDS Information

Provider	Language
SigmaAldrich	English

(+)-CHLOROMETHYL MENTHYL ETHER Usage And Synthesis

Chemical Properties

clear colorless liquid

Uses

(+)-Chloromethyl menthyl ether can be used:

As a starting material for the synthesis of 1-methyl-3-(+)-methylmenthoxide imidazolium chloride, a key intermediate for the preparation of Ag(I) N-heterocyclic carbene, applicable as a catalyst in the diboration of alkenes.
As a substrate in the synthesis of commercially important O-substituted α-methoxymethylketones.
To determine enantiomeric excess (ee) of an iron chiral auxiliary named [Fe(CO)(η;⁵- C₂H₅)(PPh₃)COCH₃].

(+)-CHLOROMETHYL MENTHYL ETHER Preparation Products And Raw materials

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