DIETHYL ALLYLPHOSPHONATE

DIETHYL ALLYLPHOSPHONATE
  • CAS No.:1067-87-4
Other grades of this product :
DIETHYL ALLYLPHOSPHONATE Basic information
Product Name:DIETHYL ALLYLPHOSPHONATE
Synonyms:DIETHYL(PROP-1(E)-ENYL)PHOSPHONATE;DIETHYL(PROP-2-(E)-ENYL)PHOSPHONATE;DIETHYL-(ALLYLPHOSPHONAT);DIETHYL ALLYLPHOSPHONATE;DIETHYL-(2-PROPENYL)-PHOSPHONAT;DIETHYL(2-PROPENYL)PHOSPHONATE;DIETHYL (1-PROPENYL)PHOSPHONATE;AURORA KA-1466
CAS:1067-87-4
MF:C7H15O3P
MW:178.17
EINECS:619-646-5
Product Categories:C-C Bond Formation;Horner-Wadsworth-Emmons Reagents;Olefination
Mol File:1067-87-4.mol
DIETHYL ALLYLPHOSPHONATE Chemical Properties
Boiling point 46 °C/0.35 mmHg (lit.)
density 1,035 g/cm3
vapor pressure 55.2Pa at 25℃
refractive index n20/D 1.4340(lit.)
Fp 224 °F
form Liquid
color Clear colorless
LogP1.33 at pH7
Surface tension56.4-60.9mN/m at 1g/L and 19℃
CAS DataBase Reference1067-87-4(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
DIETHYL ALLYLPHOSPHONATE Usage And Synthesis
Chemical Propertiesclear colorless liquid
UsesReactant for:
  • Copolymerization of phosphonated allyl monomers and maleic anhydride
  • Enantioselective synthesis of solamin type mono-THF acetogenins
  • RCM reaction yielding oxaphospholene and oxaphosphinene heterocycles
  • Synthesis of spongistatin 2 using Wittig coupling
  • Stereoselective synthesis of pentacyclic furanosteroids
  • Preparation of protected polyhydroxylated β -amino acid constitutents of microsclerodermins
Synthesis Reference(s)Synthetic Communications, 22, p. 2219, 1992 DOI: 10.1080/00397919208019075Synthesis, p. 563, 1986 DOI: 10.1055/s-1986-31704

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