| TRIS(TRIMETHYLSILYL)METHANE Basic information |
| Product Name: | TRIS(TRIMETHYLSILYL)METHANE |
| Synonyms: | TRIS(TRIMETHYLSILYL)METHANE 97+%;Tris(trimethylsilyl)methane,min.97%;Tris(trimethylsilyl)methane, min. 97%;2,2,4,4-Tetramethyl-3-(trimethylsilyl)-2,4-disilapentane;Methanetriyltris(trimethylsilane);Methylidynetris(trimethylsilane);Tris(trimethylsilyl)methane,93%;1,1',1''-Methylidynetris[1,1,1-trimethylsilane] |
| CAS: | 1068-69-5 |
| MF: | C10H28Si3 |
| MW: | 232.59 |
| EINECS: | |
| Product Categories: | organosilicon compounds;Organometallic Reagents;Organosilicon;Others |
| Mol File: | 1068-69-5.mol |
| TRIS(TRIMETHYLSILYL)METHANE Chemical Properties |
| Boiling point | 55-56 °C/2 mmHg (lit.) |
| density | 0.827 g/mL at 25 °C (lit.) |
| refractive index | n |
| Fp | 170 °F |
| solubility | sol common organic solvents. |
| form | liquid |
| color | colorless |
| Specific Gravity | 0.827 |
| Hydrolytic Sensitivity | 1: no significant reaction with aqueous systems |
| BRN | 1850371 |
| CAS DataBase Reference | 1068-69-5 |
| Safety Information |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26-36 |
| WGK Germany | 3 |
| TSCA | No |
| MSDS Information |
| Provider | Language |
|---|---|
| SigmaAldrich | English |
| ACROS | English |
| TRIS(TRIMETHYLSILYL)METHANE Usage And Synthesis |
| Chemical Properties | CLEAR COLORLESS LIQUID |
| Physical properties | bp 219 °C, 93–95 °C/13.5 mmHg; d 0.836 g cm?3; n20 D 1.4657. |
| Uses | Sterically demanding "risyl"group. |
| Uses | Tris(trimethylsilyl)methane is precursor of (Me3Si)3CLi, useful to introduce bulky tris(trimethylsilyl)methyl (trisyl) group; Peterson alkenation reagent. It takes part in the reactions of Synthesis of Tris(trimethylsilyl)methyl Bromide, Metalation, Formation of Bis(trimethylsilyl)methyllithium, Hydrosilylation of Double Bonds, Intramolecular Reactions, Intermolecular Reactions, Nonradical Reactions etc. |
| TRIS(TRIMETHYLSILYL)METHANE Preparation Products And Raw materials |
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