Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride

Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride
  • CAS No.:1033772-47-2
Other grades of this product :
Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride Basic information
Product Name:Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride
Synonyms:Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride;Bis[(2-diMethylaMino)phenyl]aMine nickel(II) chloride,98%;(SP-4-3)-Chloro[N2-[2-(diMethylaMino-κN)phenyl]-N1,N1-diMethyl-1,2-benzenediaMinato-κN1,κN2]nickel;Nickamine;Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride >=97% (AT);Bis[(2-dimethylamino)phenyl]aminenickel(II)chloride>=98.0%(AT);]amine nickeL
CAS:1033772-47-2
MF:C16H20ClN3Ni
MW:348.5
EINECS:
Product Categories:
Mol File:1033772-47-2.mol
Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride Chemical Properties
form Solid
Safety Information
WGK Germany 3
MSDS Information
Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride Usage And Synthesis
UsesBis[(2-dimethylamino)phenyl]amine Nickel(II) Chloride is a new pincer-type bis(amido)amine (NN2) ligand. The Ni(II) alkyl complexes react cleanly with alkyl halides including chlorides to form C-C cou pled products and Ni(II) halides.
UsesCatalyst for:
  • Alkyl-alkyl Kumada coupling of secondary alkyl halides
  • Direct alkylation of heterocyclic C-H bonds
  • Sonogashira coupling of nonactivated alkyl halides
  • Kumada-Corriu-Tamao coupling of nonactivated alkyl halides with aryl and heteroaryl nucleophiles
Reactant of pincer NN2 ligand leading to selective carbon-carbon bond formation
Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride Preparation Products And Raw materials

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