1-HEXYN-3-OL

1-HEXYN-3-OL
  • CAS No.:105-31-7
Other grades of this product :
1-HEXYN-3-OL Basic information
Product Name:1-HEXYN-3-OL
Synonyms:1-Propylpropargyl alcohol;1-propylpropargylalcohol;3-Hydroxy-1-hexyne;Propylethinylcarbinol;3-Hydroxyhexyne;1-HEXYN-3-OL;1-HEXYNE-3-OL;Hexynol
CAS:105-31-7
MF:C6H10O
MW:98.14
EINECS:203-286-7
Product Categories:Acetylenes;Acetylenic Alcohols & Their Derivatives;Alkynes;Organic Building Blocks;Terminal
Mol File:105-31-7.mol
1-HEXYN-3-OL Chemical Properties
Melting point -80°C
Boiling point 118 °C
density 0.873 g/mL at 25 °C
refractive index n20/D 1.431
Fp 117 °F
storage temp. Sealed in dry,Room Temperature
form clear liquid
pka13.28±0.20(Predicted)
color Colorless to Light orange to Yellow
BRN 1739419
InChIKeyLTFTWJYRQNTCHI-UHFFFAOYSA-N
CAS DataBase Reference105-31-7(CAS DataBase Reference)
EPA Substance Registry System1-Hexyn-3-ol (105-31-7)
Safety Information
Hazard Codes T+
Risk Statements 10-25-27-41
Safety Statements 26-28-36/37/39-45
RIDADR UN 2929 6.1/PG 1
WGK Germany 3
RTECS MR0181000
TSCA Yes
HazardClass 3
PackingGroup III
HS Code 29052900
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
1-HEXYN-3-OL Usage And Synthesis
Chemical PropertiesLight-yellow liquid; strong odor. Slightly soluble in water; miscible with most hydrocarbons, chlorinated solvents, ketones, alcohols, and glycols.
Uses1-Hexyn-3-ol may be used in the synthesis of racemic 3-hydroxy-2-hexanone. It may also be used in the preparation of 1,2,3-triazoles.
UsesCorrosion inhibitor against mineral acids, hightemperature oil-well-acidizing inhibitor.
General Description1-Hexyn-3-ol is a terminal propargylic alcohol. It undergoes microwave-accelerated coupling-isomerization reaction (MACIR) with (hetero)aryl halides to afford the corresponding enone.
HazardToxic by ingestion and inhalation, absorbed by skin. Probably flammable.
1-HEXYN-3-OL Preparation Products And Raw materials
Preparation ProductsLeaf alcohol

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