Other grades of this product :
| [Ir{dFCF3ppy}2(bpy)]PF6 Basic information | | Reaction |
| Product Name: | [Ir{dFCF3ppy}2(bpy)]PF6 | | Synonyms: | [Ir{dFCF3ppy}2(bpy)]PF6;Bis [2- (2,4-difluorophenyl) -5-trifluoromethylpyridine] [2-2'-bipyridyl] iridium hexafluorophosphate;(2,2'-BIPYRIDINE)BIS[3,5-DIFLUORO-2-[5-(TRIFLUOROMETHYL)-2-PYRIDINYL-KN][PHENYL-KC]IRIDIUM(III)HEXAFLUOROPHOSPHATE;Ir[dF(CF3)2ppy]2(bpy)]PF6;(2,2'-Bipyridine)bis[3,5-difL;uoro-2-[5-trifL;(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-kappaN][phenyl-kappaC]iridium(III) Hexafluorophosphate;(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl]phenyl]iridium(III) Hexafluorophosphate | | CAS: | 1092775-62-6 | | MF: | C34H18F16IrN4P | | MW: | 1009.6987322 | | EINECS: | | Product Categories: | | Mol File: | 1092775-62-6.mol |
| [Ir{dFCF3ppy}2(bpy)]PF6 Chemical Properties |
| storage temp. | Keep in dark place,Inert atmosphere,Room temperature | | form | Powder | | color | yellow | | Sensitive | air sensitive |
| [Ir{dFCF3ppy}2(bpy)]PF6 Usage And Synthesis |
| Reaction |
- Catalyst used for the chemo-, regio, and stereoselective trifluoromethylation of styrene.
- Photoredox catalyst used in cross-coupling: Ir/Ni dual catalysts for the synthesis of benzylic ethers.
- Iridium complex used for catalytic olefin hydroamidation enabled by proton-coupled electron transfer.
- Catalyst used for visible light photoredox cross-coupling of acyl chlorides with potassium alkoxymethyltrifluoroborates.
- Iridium catalyst used in the photoredox/nickel dual catalytic cross-coupling of secondary alkyl β-trifluoroboratoketones and –esters with aryl bromides.
- Photocatalyst used in the cross-coupling of trifluoroalkylboranes.
| | Uses | When used in tandem with a nickel catalyst, the above photoredox catalyst effects the cross-coupling of C-sp3 hybridized trifluoroborates with aryl bromides under exceptionally mild conditions. |
| [Ir{dFCF3ppy}2(bpy)]PF6 Preparation Products And Raw materials |
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![[Ir{dFCF3ppy}2(bpy)]PF6](/img/1092775-62-6.jpg "[Ir{dFCF3ppy}2(bpy)]PF6")
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