[Ir{dFCF3ppy}2(bpy)]PF6

CAS No.：1092775-62-6

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[Ir{dFCF3ppy}2(bpy)]PF6 Basic information

Reaction

Product Name:	[Ir{dFCF3ppy}2(bpy)]PF6
Synonyms:	[Ir{dFCF3ppy}2(bpy)]PF6;Bis [2- (2,4-difluorophenyl) -5-trifluoromethylpyridine] [2-2'-bipyridyl] iridium hexafluorophosphate;(2,2'-BIPYRIDINE)BIS[3,5-DIFLUORO-2-[5-(TRIFLUOROMETHYL)-2-PYRIDINYL-KN][PHENYL-KC]IRIDIUM(III)HEXAFLUOROPHOSPHATE;Ir[dF(CF3)2ppy]2(bpy)]PF6;(2,2'-Bipyridine)bis[3,5-difL;uoro-2-[5-trifL;(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-kappaN][phenyl-kappaC]iridium(III) Hexafluorophosphate;(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl]phenyl]iridium(III) Hexafluorophosphate
CAS:	1092775-62-6
MF:	C34H18F16IrN4P
MW:	1009.6987322
EINECS:
Product Categories:
Mol File:	1092775-62-6.mol

[Ir{dFCF3ppy}2(bpy)]PF6 Chemical Properties

storage temp.	Keep in dark place,Inert atmosphere,Room temperature
form	Powder
color	yellow
Sensitive	air sensitive

Safety Information

MSDS Information

[Ir{dFCF3ppy}2(bpy)]PF6 Usage And Synthesis

Reaction

Catalyst used for the chemo-, regio, and stereoselective trifluoromethylation of styrene.
Photoredox catalyst used in cross-coupling: Ir/Ni dual catalysts for the synthesis of benzylic ethers.
Iridium complex used for catalytic olefin hydroamidation enabled by proton-coupled electron transfer.
Catalyst used for visible light photoredox cross-coupling of acyl chlorides with potassium alkoxymethyltrifluoroborates.
Iridium catalyst used in the photoredox/nickel dual catalytic cross-coupling of secondary alkyl β-trifluoroboratoketones and –esters with aryl bromides.
Photocatalyst used in the cross-coupling of trifluoroalkylboranes.

Uses

When used in tandem with a nickel catalyst, the above photoredox catalyst effects the cross-coupling of C-sp³ hybridized trifluoroborates with aryl bromides under exceptionally mild conditions.

[Ir{dFCF3ppy}2(bpy)]PF6 Preparation Products And Raw materials

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