(S)-(-)-3,3'-DIBROMO-1,1'-BI-2-NAPHTHOL

(S)-(-)-3,3'-DIBROMO-1,1'-BI-2-NAPHTHOL
  • CAS No.:111795-43-8
Other grades of this product :
(S)-(-)-3,3'-DIBROMO-1,1'-BI-2-NAPHTHOL Basic information
Product Name:(S)-(-)-3,3'-DIBROMO-1,1'-BI-2-NAPHTHOL
Synonyms:(R)-3,3′-Dibromo-[1,1′-Binaphthalene]-2,2′-diol;(R)-Dibromo-1,1′-Bi-2,2′-naphthol;(R)-Dibromo-1,1′-Binaphthalene-2,2′-diol;(R)-Dibromo-1,1-Binaphthol;(R)-Dibromo-bi-2-naphthol;(R)-Dibromo-BINOL;(R)-(+)-3,3'-Dibromo-1,1'-bi-2-naphthol 97%;3-bromo-1-(3-bromo-2-hydroxy-1-naphthalenyl)-2-naphthalenol
CAS:111795-43-8
MF:C20H12Br2O2
MW:444.12
EINECS:
Product Categories:BINOL Series;Chiral Oxygen;chiral;Asymmetric Synthesis;Synthetic Organic Chemistry;BINOLs;Chiral Catalysts, Ligands, and Reagents;Privileged Ligands and Complexes
Mol File:111795-43-8.mol
(S)-(-)-3,3'-DIBROMO-1,1'-BI-2-NAPHTHOL Chemical Properties
Melting point 256-260 °C
alpha +43° (c 0.22, CHCl3)
Boiling point 469.9±40.0 °C(Predicted)
density 1.761±0.06 g/cm3(Predicted)
storage temp. Sealed in dry,Room Temperature
solubility within almost transparency in Methanol
pka6.43±0.50(Predicted)
form Powder
color White to pale yellow-beige
Safety Information
Hazard Codes Xn
Risk Statements 36/37/38-22
Safety Statements 26-36/37/39-37/39
RIDADR UN 3077 9 / PGIII
WGK Germany 3
HS Code 29081990
MSDS Information
ProviderLanguage
SigmaAldrich English
(S)-(-)-3,3'-DIBROMO-1,1'-BI-2-NAPHTHOL Usage And Synthesis
Chemical Propertieswhite to light yellow crystal powde
Uses(R)-(+)-3,3′-Dibromo-1,1′-bi-2-naphthol reacts with zirconium(IV) tert-butoxide to form a chiral zirconium complex, which can efficiently catalyze:
  • anti-selective catalytic asymmetric aldol reactions of silyl enol ethers with aldehydes
  • asymmetric intramolecular [3+2] cycloaddition of hydrazone/olefins
(S)-(-)-3,3'-DIBROMO-1,1'-BI-2-NAPHTHOL Preparation Products And Raw materials

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