(R)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BI-2-&

(R)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BI-2-&
  • CAS No.:111822-69-6
Other grades of this product :
(R)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BI-2-& Basic information
Product Name:(R)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BI-2-&
Synonyms:(R)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BI-2-&;(R)-3,3μ-Bis(triphenylsilyl)-1,1μ-bi-2-naphthol;(R)-3,3μ-Bis(triphenylsilyl)-1,1μ-binaphthalene-2,2μ-diol;(R)-(+)-3,3'-Bis(triphenylsilyl)-1,1'-bi-2,2'-naphthol;(R)-3,3'-Bis(triphenylsilyl)-1,1'-bi-2-naphthol 96%;(R)-3,3'-Bis(triphenylsilyl)-1,1'-bi-2-naphthol, 99%e.e.;[1,1'-Binaphthalene]-2,2'-diol, 3,3'-bis(triphenylsilyl)-, (1R)-;(1R)-3,3'- bis (triphenylsilyl) [1,1'- binaphthyl ]-2,2'- diol
CAS:111822-69-6
MF:C56H42O2Si2
MW:803.1
EINECS:
Product Categories:
Mol File:111822-69-6.mol
(R)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BI-2-& Chemical Properties
Melting point 103-145 °C
density 1.27±0.1 g/cm3(Predicted)
pka8.06±0.50(Predicted)
optical activity[α]20/D +114°, c = 1 in chloroform
Safety Information
Safety Statements 24/25
WGK Germany 3
HS Code 29319090
MSDS Information
(R)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BI-2-& Usage And Synthesis
Chemical PropertiesWhite powder
UsesPrecursor to a chiral Bronsted acid (674745) used to catalyze an enantioselective aza Diels-Alder reaction providing bicyclic lactams. Rare earth metal complexes of this chiral binapthol catalyze an intramolecular hydroamination of amino olefins leading to chiral pyrrolidines.
(R)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BI-2-& Preparation Products And Raw materials

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