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| tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate Basic information |
| Product Name: | tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate | | Synonyms: | (2S,3R)-6-Oxo-2,3-diphenyl-morpholine-4-carboxylic acid tert-butyl ester;(5S,6R)-(+)-4-Boc-5,6-diphenyl-2-Morpholinone, 99%;(2S,3R)-(+)-N-Boc-6-oxo-2,3-diphenylMorpholine;(5R,6S)-N-Boc-5,6-diphenyl-2-morpholinone;tert-butyl (2S,3R)-6-oxo-2,3-diphenylMorpholine-4-carboxylate;(2S,3R)-(+)-N-Boc-6-oxo-2,3-diphenylMorpholine;(2S, 3R) - (+) - N- t-butoxycarbonyl-6-oxo-2,3-diphenyl-Morpholine;(2S,3R)-tert-Butyl | | CAS: | 112741-50-1 | | MF: | C21H23NO4 | | MW: | 353.41 | | EINECS: | 627-150-5 | | Product Categories: | Chiral Building Blocks;Heterocyclic Building Blocks;API intermediates;Morpholines | | Mol File: | 112741-50-1.mol |
| tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate Chemical Properties |
| Melting point | 206 °C (dec.)(lit.) | | alpha | 86 º (c=5.5 in methylene chloride) | | Boiling point | 509.6±50.0 °C(Predicted) | | density | 1.175±0.06 g/cm3(Predicted) | | storage temp. | 2-8°C | | pka | -3.28±0.60(Predicted) | | optical activity | [α]20/D +86°, c = 5.5 in methylene chloride | | InChIKey | MRUKRSQUUNYOFK-MOPGFXCFSA-N | | CAS DataBase Reference | 112741-50-1(CAS DataBase Reference) |
| tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate Usage And Synthesis |
| Uses | (2S,3R)-(+)-N-Boc-6-oxo-2,3-diphenylmorpholine (Williams chiral auxiliary) can be used as a reactant: - In the asymmetric synthesis of cylindrospermopsin and related alkaloids via an intramolecular 1,3-dipolar cycloaddition reaction.
- To synthesize boc-3-(1-methylcyclopropyl)-D-alanine, which is used as an intermediate to prepare 4-fluoroproline-based analogs as potent tripeptide thrombin inhibitors.
- In the total synthesis of potent hepatotoxic alkaloid 7-epicylindrospermopsin by intramolecular 1,3-dipolar cycloaddition and nitroaldol reaction.
- To prepare differentially functionalized diaminoglutamic acids via radical reaction of selenide with methyl 2-acetamidoacrylate.
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| tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate Preparation Products And Raw materials |
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