(2S)-(+)-GLYCIDYL 4-NITROBENZOATE

CAS No.：115459-65-9

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(2S)-(+)-GLYCIDYL 4-NITROBENZOATE Basic information

Product Name:	(2S)-(+)-GLYCIDYL 4-NITROBENZOATE
Synonyms:	(2S)-(+)-GLYCIDYL 4-NITROBENZOATE;(S)-(+)-GLYCIDYL-4-NITROBENZOATE;(2s)-(+)-(2,3-epoxypropylester)-4-nitrobenzoate;4-nitrobenzoate,(s)-oxiranemethano;(2S)-(+)-Glycidyl 4-nitr0benzoate;4-17-00-01007 (Beilstein Handbook Reference);2,3-EPOXYPROPYLESTER-4-NITROBENZOATE;(S)-(+)-Glycidyl 4-nitrobenzoate, (S)-(+)-Oxirane-2-methanol 4-nitrobenzoate
CAS:	115459-65-9
MF:	C10H9NO5
MW:	223.18
EINECS:
Product Categories:
Mol File:	115459-65-9.mol

(2S)-(+)-GLYCIDYL 4-NITROBENZOATE Chemical Properties

Melting point	60-62 °C (lit.)
storage temp.	2-8°C
optical activity	[α]19/D +37°, c = 1.08 in chloroform
BRN	87687

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-36
WGK Germany	3
RTECS	RR0511020
F	10-21

MSDS Information

Provider	Language
SigmaAldrich	English

(2S)-(+)-GLYCIDYL 4-NITROBENZOATE Usage And Synthesis

Purification Methods

Purify glycidol by fractional distillation.The 4-nitrobenzoates have m 56o (±); m 60-62o, [] D 20 -37.9o (c 3.38 CHCl3) for R-(-)-isomer [106268-95-5];m 60-62o, [] D 20 +38o (c 1 CHCl3) for the S-(+)-isomer [115459-65-9] and are recrystallised from Et2O or Et2O/pet ether (b 40-60o) [S-isomer: Burgos et al. J Org Chem 52 4973 1987, Sowden & Fischer J Am Chem Soc 64 1291 1942.] [Beilstein 17 I 50, 17 III/IV 985, 17/3 V 9.] Gramine.

(2S)-(+)-GLYCIDYL 4-NITROBENZOATE Preparation Products And Raw materials

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