(2S)-(+)-GLYCIDYL 4-NITROBENZOATE

(2S)-(+)-GLYCIDYL 4-NITROBENZOATE
  • CAS No.:115459-65-9
Other grades of this product :
(2S)-(+)-GLYCIDYL 4-NITROBENZOATE Basic information
Product Name:(2S)-(+)-GLYCIDYL 4-NITROBENZOATE
Synonyms:(2S)-(+)-GLYCIDYL 4-NITROBENZOATE;(S)-(+)-GLYCIDYL-4-NITROBENZOATE;(2s)-(+)-(2,3-epoxypropylester)-4-nitrobenzoate;4-nitrobenzoate,(s)-oxiranemethano;(2S)-(+)-Glycidyl 4-nitr0benzoate;4-17-00-01007 (Beilstein Handbook Reference);2,3-EPOXYPROPYLESTER-4-NITROBENZOATE;(S)-(+)-Glycidyl 4-nitrobenzoate, (S)-(+)-Oxirane-2-methanol 4-nitrobenzoate
CAS:115459-65-9
MF:C10H9NO5
MW:223.18
EINECS:
Product Categories:
Mol File:115459-65-9.mol
(2S)-(+)-GLYCIDYL 4-NITROBENZOATE Chemical Properties
Melting point 60-62 °C (lit.)
storage temp. 2-8°C
optical activity[α]19/D +37°, c = 1.08 in chloroform
BRN 87687
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
RTECS RR0511020
10-21
MSDS Information
ProviderLanguage
SigmaAldrich English
(2S)-(+)-GLYCIDYL 4-NITROBENZOATE Usage And Synthesis
Purification MethodsPurify glycidol by fractional distillation.The 4-nitrobenzoates have m 56o (±); m 60-62o, [] D 20 -37.9o (c 3.38 CHCl3) for R-(-)-isomer [106268-95-5];m 60-62o, [] D 20 +38o (c 1 CHCl3) for the S-(+)-isomer [115459-65-9] and are recrystallised from Et2O or Et2O/pet ether (b 40-60o) [S-isomer: Burgos et al. J Org Chem 52 4973 1987, Sowden & Fischer J Am Chem Soc 64 1291 1942.] [Beilstein 17 I 50, 17 III/IV 985, 17/3 V 9.] Gramine.
(2S)-(+)-GLYCIDYL 4-NITROBENZOATE Preparation Products And Raw materials

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