(11bR)-2,6-Bis[3,5-bis(trifluoromethyl)phenyl]dinaphtho[2,1-d:1′,2′-f][1,3,2]dithiazepine 3,3,5,5-tetraoxide

(11bR)-2,6-Bis[3,5-bis(trifluoromethyl)phenyl]dinaphtho[2,1-d:1′,2′-f][1,3,2]dithiazepine 3,3,5,5-tetraoxide
  • CAS No.:1174193-01-1
Other grades of this product :
(11bR)-2,6-Bis[3,5-bis(trifluoromethyl)phenyl]dinaphtho[2,1-d:1′,2′-f][1,3,2]dithiazepine 3,3,5,5-tetraoxide Basic information
Product Name:(11bR)-2,6-Bis[3,5-bis(trifluoromethyl)phenyl]dinaphtho[2,1-d:1′,2′-f][1,3,2]dithiazepine 3,3,5,5-tetraoxide
Synonyms:(11bR)-2,6-Bis[3,5-bis(trifluoromethyl)phenyl]dinaphtho[2,1-d:1′,2′-f][1,3,2]dithiazepine 3,3,5,5-tetraoxide;(R)-3,3′-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1′-binaphthyl-2,2′-disulfonimide;(11bR)- 2,6-bis[3,5-bis(trifluoromethyl)phenyl]-3,3,5,5-tetraoxide-Dinaphtho[2,1-d:1',2'f][1,3,2]dithiazepine;Dinaphtho[2,1-d:1',2'-f][1,3,2]dithiazepine, 2,6-bis[3,5-bis(trifluoromethyl)phenyl]-, 3,3,5,5-tetraoxide, (11bR)-;(R)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-binaphthyl-2,2'-disulfonimide 95%
CAS:1174193-01-1
MF:C36H17F12NO4S2
MW:819.64
EINECS:
Product Categories:
Mol File:1174193-01-1.mol
(11bR)-2,6-Bis[3,5-bis(trifluoromethyl)phenyl]dinaphtho[2,1-d:1′,2′-f][1,3,2]dithiazepine 3,3,5,5-tetraoxide Chemical Properties
Melting point 325-330°C
Boiling point 787.6±70.0 °C(Predicted)
density 1.558±0.06 g/cm3(Predicted)
pka-4.30±0.20(Predicted)
optical activity[α]22/D -42.0°, c = 0.5% in chloroform
Safety Information
WGK Germany 3
MSDS Information
(11bR)-2,6-Bis[3,5-bis(trifluoromethyl)phenyl]dinaphtho[2,1-d:1′,2′-f][1,3,2]dithiazepine 3,3,5,5-tetraoxide Usage And Synthesis
UsesChiral Bronsted acid demonstrated in Mukaiyama aldol reactions and Friedel-Crafts alkylation of indoles with sulfonyl imines. Precursor to chiral fluorinating reagent.A Powerful Chiral Counteranion Motif for Asymmetric CatalysisChiral Sulfonimide as a Br?nsted Acid Organocatalyst for Asymmetric Friedel-Crafts Alkylation of Indoles with IminesChiral N-Fluorodibenzenesulfonimide Analogues for Enantioselective Electrophilic Fluorination and Oxidative Fluorination
(11bR)-2,6-Bis[3,5-bis(trifluoromethyl)phenyl]dinaphtho[2,1-d:1′,2′-f][1,3,2]dithiazepine 3,3,5,5-tetraoxide Preparation Products And Raw materials

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