N-BENZYLCINCHONIDINIUM BROMIDE

N-BENZYLCINCHONIDINIUM BROMIDE
  • CAS No.:118089-84-2
Other grades of this product :
N-BENZYLCINCHONIDINIUM BROMIDE Basic information
Product Name:N-BENZYLCINCHONIDINIUM BROMIDE
Synonyms:N-Benzylcinchonidinium bromide 97%;N-BENZYLCINCHONIDINIUM BROMIDE
CAS:118089-84-2
MF:C26H29BrN2O
MW:465.43
EINECS:
Product Categories:Asymmetric Synthesis;Chiral Catalysts, Ligands, and Reagents;Phase Transfer Reaction
Mol File:118089-84-2.mol
N-BENZYLCINCHONIDINIUM BROMIDE Chemical Properties
Melting point 190 °C (dec.)(lit.)
optical activity[α]20/D 138°, c = 1 in chloroform
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
MSDS Information
N-BENZYLCINCHONIDINIUM BROMIDE Usage And Synthesis
UsesN-Benzylcinchonidinium bromide (BCDBr) can be used:
  • To prepare various 4-(bromomethyl)benzenesulfonamides, which are employed as catalysts for asymmetric benzylation reactions.
  • As a phase transfer catalyst in the synthesis of organogelators via Michael addition reaction.
  • To catalyze the enantioselective alkylation of tert-butyl glycinate-benzophenone Schiff base furnishing the corresponding chiral α-amino acid.
  • To resolve symmetric biaryldiols via formation of inclusion complex with diols.
General DescriptionN-Benzylcinchonidinium bromide is a chiral phase-transfer catalyst (PTC).
N-BENZYLCINCHONIDINIUM BROMIDE Preparation Products And Raw materials

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