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| THIOPHENOL COPPER(I) SALT Basic information |
| Product Name: | THIOPHENOL COPPER(I) SALT | | Synonyms: | phenylthiocopper;Copper(I) thiophenoxide, Phenylthiocopper(I), Thiophenol copper(I) salt;COPPER(1) THIOPHENOXIDE;PhSCu;Copper(I) thiophenolate >=98.0% (RT) | | CAS: | 1192-40-1 | | MF: | C6H5SCu | | MW: | 0 | | EINECS: | | Product Categories: | | Mol File: | 1192-40-1.mol |
| THIOPHENOL COPPER(I) SALT Chemical Properties |
| Melting point | 280 °C (dec.)(lit.) | | BRN | 3709171 |
| THIOPHENOL COPPER(I) SALT Usage And Synthesis |
| Uses | Reagents used as the source of nucleophilic phenyl sulfide for preparation of lithiumalkyl(phenylthio)cuprates and organophosphinecopper(I) phenylthiolatecomplexes | | Purification Methods | The Cu salt can be extracted from a thimble (Soxhlet) with boiling MeOH. It is a green-brown powder which gives a yellow-green solution in pyridine. Wash it with EtOH and dry it in a vacuum. It can be precipitated from a pyridine solution by adding H2O, collecting the precipitate, washing it with EtOH and drying in a vacuum. [Posner et al. Synthesis 662 1974, Krebs et al. Chem Ber 90 425 1957, Beilstein 6 IV 1465.] |
| THIOPHENOL COPPER(I) SALT Preparation Products And Raw materials |
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