Lead zirconate

Lead zirconate
  • CAS No.:12060-01-4
Other grades of this product :
Lead zirconate Basic information
Product Name:Lead zirconate
Synonyms:dioxido(oxo)zirconium,lead(2+);Lead zirconate (II);Lead(II) zirconate, 99.7% trace metals basis excluding Hf;Lead(II) zirconium oxide;LEAD ZIRCONATE;LEAD ZIRCONIUM OXIDE;LEAD(II) ZIRCONATE;leadzirconiumoxide(pbzro3)
CAS:12060-01-4
MF:O3PbZr
MW:346.42
EINECS:235-039-4
Product Categories:inorganic compound;Ceramics;Metal and Ceramic Science;Zirconates
Mol File:12060-01-4.mol
Lead zirconate Chemical Properties
Melting point 1570℃
density 7 g/cm3
solubility Insoluble in all solvents.
form Powder
Specific Gravity7
color off-white
Water Solubility insoluble H2O, alkalies; soluble mineral acids [KIR78]
Exposure limitsACGIH: TWA 0.05 mg/m3; TWA 5 mg/m3; STEL 10 mg/m3NIOSH: IDLH 25 mg/m3; IDLH 100 mg/m3; TWA 5 mg/m3; TWA 0.050 mg/m3; STEL 10 mg/m3
CAS DataBase Reference12060-01-4(CAS DataBase Reference)
EPA Substance Registry SystemLead zirconium oxide (PbZrO3) (12060-01-4)
Safety Information
Hazard Codes T,N
Risk Statements 61-20/22-33-50/53-62
Safety Statements 53-45-60-61
RIDADR UN 2291 6.1/PG 3
WGK Germany 3
TSCA Yes
HazardClass 9
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
Lead zirconate Usage And Synthesis
Chemical Propertiescolorless cub perovskite >230°, pseudotetr or ortho-rhomb <230°C; can be obtained by heating stoichiometric amounts of lead and zirconium oxides; has high piezoelectric properties; used in high power acoustic transducer, hydrophones, and as a 99.7% pure sputtering target for thin film capacitors [STR93] [CER91] [KIR78]
UsesLead zirconate (PbZrO3, PZ) is practically applied in the area of electroceramics. It is an end member of the family of a well-known FE oxide solid solution, PbZr1 ? xTixO3 (PZT). Lead zirconate titanate (PbZr1-xTixO3, or PZT) ceramics are extensively used in ferroelectric devices due to their excellent piezoelectric, dielectric, and elastic properties.
Production MethodsLead zirconate has two colorless crystal structures: a cubic perovskite form above 230 °C (Curie point) and a pseudotetragonal or orthorhombic form below 230 °C. It is insoluble in water and aqueous alkalies, but soluble in strong mineral acids. Lead zirconate is usually prepared by heating together the oxides of lead and zirconium in the proper proportion. It readily forms solid solutions with other compounds with the ABO3 structure, such as barium zirconate or lead titanate. Mixed lead titanate-zirconates have particularly high piezoelectric properties. They are used in high power acoustic-radiating transducers, hydrophones, and specialty instruments.
Lead zirconate Preparation Products And Raw materials

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