GERMANIUM NITRIDE

GERMANIUM NITRIDE
  • CAS No.:12065-36-0
Other grades of this product :
GERMANIUM NITRIDE Basic information
Description References
Product Name:GERMANIUM NITRIDE
Synonyms:trigermanium tetranitride;GERMANIUM NITRIDE, 99.99+%;germanium(iii) nitride;GERMANIUM NITRIDE;GERMANIUM TETRANITRIDE;Germanium(III) nitride >=99.99% trace metals basis;PubChem ID: 16684757;GERMANIUM NITRIDE ISO 9001:2015 REACH
CAS:12065-36-0
MF:Ge3N4
MW:273.95
EINECS:235-064-0
Product Categories:Nitrides;Ceramics;Metal and Ceramic Science
Mol File:12065-36-0.mol
GERMANIUM NITRIDE Chemical Properties
Melting point >850 °C (dec.)(lit.)
density 5.35 g/mL at 25 °C(lit.)
form orthorhombic crystals
Specific Gravity5.35
Water Solubility insoluble H2O; does not react with most mineral acids, aqua regia or caustic solutions [KIR78] [CRC10]
EPA Substance Registry SystemGermanium nitride (Ge3N4) (12065-36-0)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
TSCA Yes
MSDS Information
ProviderLanguage
SigmaAldrich English
GERMANIUM NITRIDE Usage And Synthesis
DescriptionGermanium nitride (Ge3N4) does not occur in nature as a compound. It can be produced by reacting germanium with ammonia. It can be applied as a passivation layers to germanium-based radiation detectors. Germanium Nitride is reported to be used as a water-insoluble gate dielectric film in metal oxide semiconductor field effect transistor with germanium channel.2 It is used in etchant formulation, which was originally developed for silicon oxynitride.3
References
  1. G. Maggioni, S. Carturan, L. Fiorese, N. Pinto, F. Caproli, D. R. Napoli, M. Giarola, G. Mariotto, Germanium nitride and oxynitride films for surface passivation of Ge radiation detectors, 2017, vol. 393, pp.119-126
  2. H. Kondo, I. Yanagi, M. Sakashita, A. Sakai, M. Ogawa, S. Zaima, Electrical properties and bonding structures of germanium nitride/Ge(100) structures formed by radical nitridation, 2006, vol. 3, pp. 287-289
  3. P. Walker, W. H. Tarn, CRC Handbook of Metal Etchants, 1991, ISBN 0-8493-6323-6
Chemical Propertiesbrownish-white powder(s); -200 mesh with 99.999% purity; prepared by reacting Ge powder(s) and ammonia at 700°C–850°C; ortho-rhomb; a=1.384nm, b=0.406 nm, c=0.818 nm [CIC73] [CER91] [CRC10]
GERMANIUM NITRIDE Preparation Products And Raw materials

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