2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE

2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE
  • CAS No.:120666-13-9
Other grades of this product :
2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE Basic information
Reaction
Product Name:2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE
Synonyms:2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE;2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1- &;2,89-Trimethyl-2,5,89-tetraaza-1-phosphabicyclo[3.3.3]undecaneverkadesuperbase;VERKADE SUPERBASE;2,8,9-Trimethyl-1-phospha-2,5,8,9-tetraazabicyclo[3.3.3]undecane;Verkadebase;4,6,11-trimethyl-1,4,6,11-tetraza-5-phosphabicyclo[3.3.3]undecane;2,5,8,9-Tetraaza-1-phosphabicyclo[3.3.3]undecane, 2,8,9-trimethyl-
CAS:120666-13-9
MF:C9H21N4P
MW:216.26
EINECS:
Product Categories:Achiral Phosphine;Alkyl Phosphine;organophosphine ligand
Mol File:120666-13-9.mol
2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE Chemical Properties
Melting point 110-115 °C(lit.)
Boiling point 263.9±39.0 °C(Predicted)
pka10.43±0.20(Predicted)
form solid
color white waxy
Sensitive moisture sensitive, store cold
BRN 4970285
Safety Information
WGK Germany 3
MSDS Information
2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE Usage And Synthesis
ReactionExceedingly strong, non-ionic Brønsted and Lewis base useful in a variety of organic transformations.
Uses2,8,9-Trimethyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane (CAS# 120666-13-9) is a useful catalyst for the direct α-?arylation of nitriles with aryl chlorides and aryl bromides. It is also used as a catalyst in carbon dioxide reduction to methylamines under metal-free conditions.
2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE Preparation Products And Raw materials
Preparation Products5-PHENYL-1,3-OXAZOLE-4-CARBONYL CHLORIDE

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