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| 2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE Basic information | | Reaction |
| Product Name: | 2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE | | Synonyms: | 2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE;2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1- &;2,89-Trimethyl-2,5,89-tetraaza-1-phosphabicyclo[3.3.3]undecaneverkadesuperbase;VERKADE SUPERBASE;2,8,9-Trimethyl-1-phospha-2,5,8,9-tetraazabicyclo[3.3.3]undecane;Verkadebase;4,6,11-trimethyl-1,4,6,11-tetraza-5-phosphabicyclo[3.3.3]undecane;2,5,8,9-Tetraaza-1-phosphabicyclo[3.3.3]undecane, 2,8,9-trimethyl- | | CAS: | 120666-13-9 | | MF: | C9H21N4P | | MW: | 216.26 | | EINECS: | | Product Categories: | Achiral Phosphine;Alkyl Phosphine;organophosphine ligand | | Mol File: | 120666-13-9.mol |
| 2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE Chemical Properties |
| Melting point | 110-115 °C(lit.) | | Boiling point | 263.9±39.0 °C(Predicted) | | pka | 10.43±0.20(Predicted) | | form | solid | | color | white waxy | | Sensitive | moisture sensitive, store cold | | BRN | 4970285 |
| 2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE Usage And Synthesis |
| Reaction | Exceedingly strong, non-ionic Brønsted and Lewis base useful in a variety of organic transformations.
| | Uses | 2,8,9-Trimethyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane (CAS# 120666-13-9) is a useful catalyst for the direct α-?arylation of nitriles with aryl chlorides and aryl bromides. It is also used as a catalyst in carbon dioxide reduction to methylamines under metal-free conditions. |
| 2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE Preparation Products And Raw materials |
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