Product

2-Methoxy-5-methylaniline

CAS No.：120-71-8

Other grades of this product :

2-Methoxy-5-methylaniline Basic information

Product Name:	2-Methoxy-5-methylaniline
Synonyms:	2-Amino-4-methylphenolmethylether;2-Amino-p-cresol methyl ether;2-Amino-p-cresolmethylether;m-amino-p-cresol,methylester;meta-amino-para-cresol,methylether;NCI-C02982;o-Anisidine, 5-methyl-;o-anisidine,5-methyl-(8ci)
CAS:	120-71-8
MF:	C8H11NO
MW:	137.18
EINECS:	204-419-1
Product Categories:	Anilines, Aromatic Amines and Nitro Compounds;Intermediates of Dyes and Pigments
Mol File:	120-71-8.mol

2-Methoxy-5-methylaniline Chemical Properties

Melting point	50-52 °C (lit.)
Boiling point	235 °C (lit.)
density	1.0252 (rough estimate)
vapor density	4.7 (vs air)
vapor pressure	2.6Pa at 20℃
refractive index	1.5647 (estimate)
Fp	>230 °F
storage temp.	Room Temperature, under inert atmosphere
solubility	Chloroform (Slightly), Ethyl Acetate, Methanol (Slightly)
form	Crystalline Chunks
pka	4.66±0.10(Predicted)
color	Brown to black
Water Solubility	Slightly soluble in hot water.
BRN	637071
Stability:	Air Sensitive
InChIKey	WXWCDTXEKCVRRO-UHFFFAOYSA-N
LogP	1.65 at 23℃ and pH7
CAS DataBase Reference	120-71-8(CAS DataBase Reference)
NIST Chemistry Reference	Benzenamine, 2-methoxy-5-methyl-(120-71-8)
IARC	2B (Vol. 27, Sup 7) 1987
EPA Substance Registry System	p-Cresidine (120-71-8)

Safety Information

Hazard Codes	T,Xi
Risk Statements	45-22
Safety Statements	53-45
WGK Germany	3
RTECS	BZ6720000
F	9
HazardClass	IRRITANT
HS Code	29222990
Hazardous Substances Data	120-71-8(Hazardous Substances Data)

MSDS Information

Provider	Language
2-Methoxy-5-methylaniline	English
SigmaAldrich	English
ACROS	English

2-Methoxy-5-methylaniline Usage And Synthesis

Chemical Properties	brown to black crystalline chunks
Chemical Properties	p-Cresidine is a white crystalline solid.
Uses	p-Cresidine is a reagent used in the preparation of enaminones acting as anticonvulsants. Also used in the preparation of crescent oligoamides. Dyes and metabolites, Environmental Testing.
Uses	2-Methoxy-5-methylaniline was used in the synthesis of 4-(4-Amino-5-methoxy-2-methylphenylazo)-5-hydroxy-naphthalene-2,7-disulfonic acid. 2-Methoxy-5-methylaniline was used to analyse the application of polymeric ionic liquids as selective solid-phase microextraction sorbent coatings for the analysis of genotoxic impurities and structurally alerting compounds such as alkyl halides and aromatics. 2-Methoxy-5-methylaniline was used in a study to develop a sensitive analytical method for the determination of aromatic amines found in commercial hair dyes using high liquid chromatography coupled to an electrochemical detector by using the ionic liquid 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide in the mobile phase.
Uses	p-Cresidine is a reagent used in the preparation of enaminones acting as anticonvulsants. Also used in the preparation of crescent oligoamides.
General Description	White to silver-gray odorless crystals.
Air & Water Reactions	Insoluble in water.
Reactivity Profile	2-Methoxy-5-methylaniline is sensitive to moisture and temperatures greater than 104°F. Incompatible with strong oxidizing agents .
Hazard	A possible carcinogen.
Fire Hazard	2-Methoxy-5-methylaniline is nonflammable.
Safety Profile	Confirmed carcinogen with experimental carcinogenic and neoplastigenic data. Moderately toxic by ingestion. A skin and eye irritant. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx. See also ESTERS.
Potential Exposure	p-Cresidine is used as an intermediate in the production of various azodyes, printing inks, and pigments; including 11 dyes that are produced commercially in the United States. Human exposure to p-Cresidine occurs primarily through inhalation of
Carcinogenicity	p-Cresidine is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity from studies in experimental animals.
Shipping	UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required
Incompatibilities	Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides.

2-Methoxy-5-methylaniline Preparation Products And Raw materials

Raw materials

Sodium hydroxide-->Dimethyl sulfate-->Sodium sulfide-->4-Chlorotoluene-->4-Chloro-2-nitrotoluene-->4-Methylanisole-->4-Chloro-3-nitrotoluene-->N-BENZYLDIETHYLAMINE-->(4-methoxy-3-nitrophenyl)methylene diacetate-->2-azido-1-methoxy-4-methylbenzene-->4-Chloro-2-methoxy-5-methylaniline-->4-Methyl-2-nitroanisole-->2-Nitro-p-cresol-->Hydrochloric acid

Preparation Products

Direct Blend Blue-->Direct Blending Yellow D-3RNL-->Reactive Yellow 84-->Direct Green 26-->Direct Violet 9-->tetrasodium 3,3'-[(1,6-dihydro-6-oxo-1,3,5-triazine-2,4-diyl)bis[imino(5-methoxy-2-methyl-4,1-phenylene)azo]]bis(naphthalene-1,5-disulphonate)-->Direct Grey D-->DIRECT VIOLET 51-->tetrasodium 4,4'-[carbonylbis[imino(5-methoxy-2-methyl-4,1-phenylene)azo]]bis[5-hydroxynaphthalene-2,7-disulphonate]-->trisodium 4-hydroxy-5-[[4-[[1-hydroxy-6-(phenylamino)-3-sulphonato-2-naphthyl]azo]-5-methoxy-2-methylphenyl]azo]naphthalene-2,7-disulphonate-->Direct Yellow L-5R-->4-Amino-5-methoxy-2-methylbenzensulfonic acid-->DIRECT GREEN 26-->DISPERSE BLACK 2

Welcome！

Please leave a message for us or use the following ways to contact us, we will reply to you as soon as possible, and provide you with the most sincere service, thank you.

NO. 18 ,Wujiang Road, Wulidian Street, Jiangbei District, Chongqing
+86-23-6139-8061 +86-13650506873
danny@chemdad.com sales@chemdad.com
www.chemdad.com
WhatsApp +86-13650506873