ANISYL FORMATE

ANISYL FORMATE
  • CAS No.:122-91-8
Other grades of this product :
ANISYL FORMATE Basic information
Product Name:ANISYL FORMATE
Synonyms:4-methoxy-benzenemethanoformate;anisyl;Benzenemethanol,4-methoxy-,formate;FEMA 2101;ANISYL FORMATE;4-METHOXYBENZYL FORMATE;ANISYL FORMATE 90+% FCC;Formic acid 4-methoxybenzyl ester
CAS:122-91-8
MF:C9H10O3
MW:166.17
EINECS:204-582-9
Product Categories:
Mol File:122-91-8.mol
ANISYL FORMATE Chemical Properties
Boiling point 220 °C(lit.)
density 1.035 g/mL at 25 °C(lit.)
vapor pressure 6.159Pa at 25℃
refractive index n20/D 1.523(lit.)
FEMA 2101 | ANISYL FORMATE
Fp 113 °C
Water Solubility 2.679g/L at 25℃
JECFA Number872
LogP1.61 at 25℃
EPA Substance Registry SystemBenzenemethanol, 4-methoxy-, formate (122-91-8)
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22-36/37/38
Safety Statements 26
WGK Germany 3
toxicityThe acute oral LD50 value in rats was reported as 1.55 ml/kg and the acute dermal LD50 value in rabbits exceeded 5 g/kg(Levenstein, 1975).
MSDS Information
ProviderLanguage
SigmaAldrich English
ANISYL FORMATE Usage And Synthesis
Chemical PropertiesColorless liquid; lilac odor. Soluble in 5.5 volumes of 70% alcohol. Combustible.
Chemical PropertiesAnisyl formate has a floral, sweet, floral, herbaceous-green odor.
OccurrenceReported found in Vanilla fragrans and Ribes species.
UsesPerfumery, flavoring.
UsesAnisyl formate is a synthetic flavoring agent that is a fairly stable, colorless to light yellow liquid of floral odor. It should be stored in glass, tin, or resin-lined containers. It is used in berry flavors for applications in beverages, candy, and baked goods at 3–10 ppm.
PreparationBy direct esterification of anisic alcohol with formic acid.
Aroma threshold valuesOdor characteristics are sweet, spicy, vanilla-like with powdery fruity nuances.
Taste threshold valuesTaste characteristics at 50 ppm: sweet, vanilla, spice, with fruity heliotropine-like nuances.
Flammability and ExplosibilityNotclassified
MetabolismEsters of benzyl alcohol, such as the acetate, are rapidly hydrolysed in vivo to benzyl alcohol, which is then oxidized. The expected general reaction of primary aromatic alcohols in the animal body is oxidation to the corresponding aromatic acid, which is usually excreted as a glycine conjugate and to a lesser extent as an ester glucuronide. In rabbits, benzyl alcohol is almost entirely converted to benzoic acid, which is excreted mainly as hippuric acid . In substituted anisoles with a carboxyl group or a potential carboxyl group attached to the aromatic ring, the ether link is relatively stable(Williams, 1959).

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