(PENTAFLUOROETHYL)TRIMETHYLSILANE

(PENTAFLUOROETHYL)TRIMETHYLSILANE
  • CAS No.:124898-13-1
Other grades of this product :
(PENTAFLUOROETHYL)TRIMETHYLSILANE Basic information
Product Name:(PENTAFLUOROETHYL)TRIMETHYLSILANE
Synonyms:(PENTAFLUOROETHYL)TRIMETHYLSILANE;TRIMETHYLPENTAFLUOROETHYLSILANE;(Pentafluoroethyl)trimethylsilane 97%;(Pentafluoroethyl)trimethylsilane97%;Silane, trimethyl(1,1,2,2,2-pentafluoroethyl)-;1,3,6-Trimethyl-2-oxo-2,3-dihydro-1H-benzoimidazole-5-carbaldehyde;triMethyl(perfluoroethyl)silane;Pentafluoro(trimethylsilyl)ethane, (Perfluoroethyl)trimethylsilane
CAS:124898-13-1
MF:C5H9F5Si
MW:192.2
EINECS:
Product Categories:
Mol File:124898-13-1.mol
(PENTAFLUOROETHYL)TRIMETHYLSILANE Chemical Properties
Boiling point 60 °C
density 1.095 g/mL
refractive index 1.3270
Fp -17℃
solubility Miscible with tetrahydrofuran.
form liquid
color colorless
Specific Gravity1.05
Hydrolytic Sensitivity4: no reaction with water under neutral conditions
Sensitive Moisture Sensitive
CAS DataBase Reference124898-13-1(CAS DataBase Reference)
EPA Substance Registry System(Pentafluoroethyl)trimethylsilane (124898-13-1)
Safety Information
Hazard Codes Xi
Risk Statements 11-36/37/38
Safety Statements 26-36/37/39
RIDADR 1993
Hazard Note Irritant
TSCA No
HazardClass 3
PackingGroup II
HS Code 2931900090
MSDS Information
(PENTAFLUOROETHYL)TRIMETHYLSILANE Usage And Synthesis
UsesSilicon-based fluorinating reagents for the efficient trifluoromethylation of carbonyls and ethylene diamines. Precursors used for metal-mediated trifluoromethylation of aromatic, heteroaromatic, vinyl substrates, etc.
Uses(Pentafluoroethyl)trimethylsilane acts as a silicon-based fluorinating reagent for trifluoromethylation of carbonyls and ethylene diamines. It is also employed as a precursor for metal-mediated trifluoromethylation of aromatic, heteroaromatic and vinyl substrates.
UsesTrimethylpentafluoroethylsilane ((Pentafluoroethyl)trimethylsilane) may be used as a perfluoroalkylating reagent for the synthesis of the following quinoline derivatives:
  • 5-bromo-2-(perfluoroethyl)quinoline
  • 8-methoxy-2-(perfluoroethyl)quinoline
  • 1-(perfluoroethyl)isoquinoline
  • 8-(tert-butoxy)-5,7-dichloro-2-(perfluoroethyl)quinolone
It may also be used in the synthesis of pentafluoroethylcyclohexanes.
General DescriptionTrimethylpentafluoroethylsilane ((Pentafluoroethyl)trimethylsilane) is a perfluoroalkylsilane. Alkyl triflates undergo nucleophilic pentafluoroethylation with trimethylpentafluoroethylsilane to form the corresponding pentafluoroethylated alkanes.
(PENTAFLUOROETHYL)TRIMETHYLSILANE Preparation Products And Raw materials

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