4-(ETHOXYCARBONYL)PHENYLZINC IODIDE

4-(ETHOXYCARBONYL)PHENYLZINC IODIDE
  • CAS No.:131379-16-3
Other grades of this product :
4-(ETHOXYCARBONYL)PHENYLZINC IODIDE Basic information
Product Name:4-(ETHOXYCARBONYL)PHENYLZINC IODIDE
Synonyms:4-(ETHOXYCARBONYL)PHENYLZINC IODIDE;4-(ETHOXYCARBONYL)PHENYLZINC IODIDE, 0.5 M SOLUTION IN TETRAHYDROFURAN;4-(ethoxycarbonyl)phenylzinc iodide solution;4-(Iodozincio)benzoic acid ethyl ester;Ethyl 4-(iodozincio)benzoate;4-(Ethoxycarbonyl)phenylzinc iodide, Packaged under Argon in resealable ChemSeal? bottles;4-(Ethoxycarbonyl)phenylzinc iodide solution 0.5M in THF;4-(Ethoxycarbonyl)phenylzinc iodide solution 0.5 in THF
CAS:131379-16-3
MF:C9H9IO2Zn
MW:341.46
EINECS:
Product Categories:Aryl;Organozinc Halides;Reike and Organozinc Reagents;Chemical Synthesis;Organometallic Reagents;Organozinc Halides;Rieke and Organozinc Reagents
Mol File:131379-16-3.mol
4-(ETHOXYCARBONYL)PHENYLZINC IODIDE Chemical Properties
density 1.018 g/mL at 25 °C
Fp 1 °F
storage temp. 2-8°C
Water Solubility Reacts with water.
Sensitive Air Sensitive
Exposure limitsACGIH: TWA 50 ppm; STEL 100 ppm (Skin)OSHA: TWA 200 ppm(590 mg/m3)NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)
CAS DataBase Reference131379-16-3
Safety Information
Hazard Codes F,Xn
Risk Statements 14-19-22-36/38-40-36/37-11
Safety Statements 16-26-33-36-36/37
RIDADR UN 2056 3/PG 2
WGK Germany 1
HazardClass 4.3
MSDS Information
ProviderLanguage
SigmaAldrich English
4-(ETHOXYCARBONYL)PHENYLZINC IODIDE Usage And Synthesis
Uses4-(Ethoxycarbonyl)phenylzinc iodide is used as pharmaceutical intermediates.
Uses4-(Ethoxycarbonyl)phenylzinc iodide can be used as:
  • A substrate in the transition metal-catalyzed cross-coupling reactions with unsaturated thioethers and thiomethyl-substituted N-heterocycles.
  • A starting material in the synthesis of indazole derived glucagon receptor antagonists.
  • A substrate in the Pd-catalyzed synthesis of 5-aryl-2-furaldehydes by reacting with 5-bromo-2-furaldehyde.
4-(ETHOXYCARBONYL)PHENYLZINC IODIDE Preparation Products And Raw materials
Preparation ProductsETHYL 4-(5-FORMYL-2-FURYL)BENZOATE

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