METHOXYALLENE; 95%DISCONTINUED 05/24/01

METHOXYALLENE; 95%DISCONTINUED  05/24/01
  • CAS No.:13169-00-1
Other grades of this product :
METHOXYALLENE; 95%DISCONTINUED 05/24/01 Basic information
Product Name:METHOXYALLENE; 95%DISCONTINUED 05/24/01
Synonyms:Propadienylmethyl ether;Allenyl methyl ether;1-Methoxypropa-1,2-diene;NSC 363923;Methoxyallene technical grade;95%DISCONTINUED 05/24/01;METHOXYALLENE; 95%DISCONTINUED 05/24/01;1,2-Propadiene, 1-methoxy-
CAS:13169-00-1
MF:C4H6O
MW:70.09
EINECS:
Product Categories:Allenes;Building Blocks;Chemical Synthesis;Organic Building Blocks
Mol File:13169-00-1.mol
METHOXYALLENE; 95%DISCONTINUED 05/24/01 Chemical Properties
Boiling point 48.2℃ (760 torr)
density 0.832 g/mL at 25 °C
refractive index n20/D 1.429
Fp -29 °C
storage temp. 2-8°C
Safety Information
Hazard Codes F
Risk Statements 11
RIDADR UN 1993 3/PG 2
WGK Germany 3
MSDS Information
METHOXYALLENE; 95%DISCONTINUED 05/24/01 Usage And Synthesis
UsesReactant involved in:• ;Multicomponent reactions with nitriles and carboxylic acids followed by cyclocondensation for synthesis of enantiopure pyridines1• ;Intermolecular hydroamination2• ;One-pot synthesis of alkoxy and (alkylsulfanyl)-substituted pyrroles and dihydropyridines3• ;Intermolecular [4+2] cycloaddition with dienes4• ;Allenyl cyclization and subsequent transformation into dicarbonyl, cyclopentenones, and butenolide compounds5• ;Insertion reactions of C-C pi-bonds into alkylidenesilacyclopropanes6
UsesReactant involved in:
  • Multicomponent reactions with nitriles and carboxylic acids followed by cyclocondensation for synthesis of enantiopure pyridines
  • Intermolecular hydroamination
  • One-pot synthesis of alkoxy and (alkylsulfanyl)-substituted pyrroles and dihydropyridines
  • Intermolecular [4+2] cycloaddition with dienes
  • Allenyl cyclization and subsequent transformation into dicarbonyl, cyclopentenones, and butenolide compounds
  • Insertion reactions of C-C pi-bonds into alkylidenesilacyclopropanes
METHOXYALLENE; 95%DISCONTINUED 05/24/01 Preparation Products And Raw materials

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