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| (S)-(+)-6,6'-DIBROMO-1,1'-BI-2-NAPHTHOL Basic information | | Reactions |
| Product Name: | (S)-(+)-6,6'-DIBROMO-1,1'-BI-2-NAPHTHOL | | Synonyms: | 6,6'-Dibromo-1,1'-binaphthalene-2,2'-diol;6,6'-Dibromo-2,2'-dihydroxy-1,1'-binaphthalene;6,6'-Dibromo-1,1'-bi-2-naphthol 97%;AURORA KA-7214;(+/-)-6,6'-DIBROMO-1,1'-BI-2-NAPHTHOL;6,6'-DIBROMO-1,1'-BI-2-NAPHTHOL;6,6'-Dibromo-1,1'-bi-2-naphthol (RAC);racemic-6,6'-Dibromo-1,1'-bi-2-naphthol,min.98% | | CAS: | 13185-00-7 | | MF: | C20H12Br2O2 | | MW: | 444.12 | | EINECS: | | Product Categories: | BINOL Series;Achiral Oxygen;Organic Building Blocks;Oxygen Compounds;Polyols | | Mol File: | 13185-00-7.mol |
| (S)-(+)-6,6'-DIBROMO-1,1'-BI-2-NAPHTHOL Chemical Properties |
| Melting point | 195-199 °C(lit.) | | Boiling point | 546.2±45.0 °C(Predicted) | | density | 1.761 | | refractive index | 1.4947 (estimate) | | storage temp. | 2-8°C | | form | Powder | | pka | 7.78±0.50(Predicted) | | color | white | | CAS DataBase Reference | 13185-00-7(CAS DataBase Reference) |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26-36 | | WGK Germany | 3 | | HS Code | 29072900 |
| (S)-(+)-6,6'-DIBROMO-1,1'-BI-2-NAPHTHOL Usage And Synthesis |
| Reactions | 1. Ligand (enantiopure version) used to prepare a chiral zirconium catalyst useful in asymmetric Strecker and Mannich-type reactions.
2. Ligand (enantiopure version) used for titanium-catalyzed enantioselective Friedel-Crafts reactions.
| | Chemical Properties | white powder | | General Description | 6,6′-Dibromo-1,1′-bi-2-naphthol is a 1,1′-bi-2-naphthol derivative. Vibrational circular dichroism (VCD), electronic circular dichroism (ECD) and optical rotatory dispersion (ORD) spectra for the enantiomers of 6,6′-dibromo-1,1′-bi-2-naphthol have been evaluated. |
| (S)-(+)-6,6'-DIBROMO-1,1'-BI-2-NAPHTHOL Preparation Products And Raw materials |
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