GERMANIUM(II) IODIDE

GERMANIUM(II) IODIDE
  • CAS No.:13573-08-5
Other grades of this product :
GERMANIUM(II) IODIDE Basic information
Description References
Product Name:GERMANIUM(II) IODIDE
Synonyms:GERMANIUM DIIODIDE;GERMANIUM DIIOIDE;Reaxys ID: 16489539;Germanium(II) iodide(GeI2);GERMANIUM(II) IODIDE, 99.99+%;Germanium(II)iodide(99.99+%-Ge)PURATREM;Germanium(II) iodide, 99.999% (metals basis);GERMANIUM(II) IODIDE
CAS:13573-08-5
MF:GeI2
MW:326.45
EINECS:236-998-1
Product Categories:Germanium Salts;Catalysis and Inorganic Chemistry;Chemical Synthesis;Crystal Grade Inorganics;Germanium;Materials Science;metal halide;Metal and Ceramic Science;Salts
Mol File:13573-08-5.mol
GERMANIUM(II) IODIDE Chemical Properties
Melting point 460°C
Boiling point 545°C
density 5.37 g/mL at 25 °C(lit.)
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
solubility Soluble in dilute hydrochloric acid.
form orange-yellow hexagonal crystals
color Yellow to brown
Specific Gravity5.73
Water Solubility soluble H2O [CRC10]
Sensitive Air & Moisture Sensitive
CAS DataBase Reference13573-08-5(CAS DataBase Reference)
EPA Substance Registry SystemGermanium iodide (GeI2) (13573-08-5)
Safety Information
Hazard Codes C
Risk Statements 34
Safety Statements 23-26-27-36/37/39-45
RIDADR UN 3260 8/PG 2
WGK Germany 3
10-19-21
TSCA Yes
HazardClass 8
PackingGroup II
HS Code 2827600090
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
GERMANIUM(II) IODIDE Usage And Synthesis
DescriptionGermanium diiodide (also named as germanium (II) iodide) is a yellow crystalline solid which decomposes on melting. Its specific density is 5.37. It can be sublimed at 240°C in a vacuum.1 It can be used to obtain high yield of germanium nanocrystals.2
References
  1. https://en.wikipedia.org/wiki/Germanium_iodide 
  2. X. Lu, B. A. Korgel, K. P. Johnston, High yield of germanium nanocrystals synthesized from germanium diiodide in solution, Chemistry of Materials, 2005, vol. 17, pp. 6479-6485
Chemical Propertiesyellow to gold flakes or powder
UsesReagent forms stable ionic adducts with carbenes.1
UsesGermanium(II) iodide acts as a reagent that forms stable ionic adducts with carbenes. It is also used in the preparation of allylgermanes by reacting with allylstannanes. Further, it reacts with allyl bromide in the presence of zinc iodide to get allylgermanium(IV), which on reacts with carbonyl compounds to give the corresponding homoallylic alcohols.
UsesReagent forms stable ionic adducts with carbenes.
GERMANIUM(II) IODIDE Preparation Products And Raw materials

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