(-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE

CAS No.：136705-75-4

Other grades of this product :

(-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE Basic information

Reactions

Product Name:	(-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE
Synonyms:	(R,R)-ME-DUPHOS-RH;(S,S)-ME-DUPHOS-RH;(-)-1,2-BIS-((2R,5R)DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I) TRIFLATE;(+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE;(+)-1,2-BIS((2S,5S)-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I) TRIFLATE;(-)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE;(-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE;(-)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)benzene(cyclooctadiene)rhodium(I) trifluoromethanesulfon
CAS:	136705-75-4
MF:	C27H40F3O3P2RhS
MW:	666.52
EINECS:
Product Categories:	Chiral Catalysts, Ligands, and Reagents;DuPhos/BPE;Privileged Ligands and Complexes;organometallic complex
Mol File:	136705-75-4.mol

(-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE Chemical Properties

Melting point	136.0-154.7 °C
storage temp.	Refrigerator (+4°C)
form	crystal
color	orange
Sensitive	air sensitive, store cold
CAS DataBase Reference	136705-75-4

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	24/25-36/37-26
WGK Germany	3

MSDS Information

Provider	Language
ACROS	English

(-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE Usage And Synthesis

Reactions	Catalyst for the enantioselective [2+2+2] cycloaddition of triynes.
Chemical Properties	orange crystalline powder
Uses	DuPhos and BPE Ligands: Highly Efficient Privileged Ligands

(-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE Preparation Products And Raw materials

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