(+)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-D-THREITOL

(+)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-D-THREITOL
  • CAS No.:137365-16-3
Other grades of this product :
(+)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-D-THREITOL Basic information
Product Name:(+)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-D-THREITOL
Synonyms:(4S,5S)-2,2-dimethyl-α4,α4,α5,α5-tetra-2-naphthalenyl-1,3-Dioxolane-4,5-dimethanol;(+)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-D-THREITOL;(4S-TRANS)-2,2-DIMETHYL-ALPHA,ALPHA,ALPHA',ALPHA'-TETRA(2-NAPHTHYL)-1,3-DIOXOLANE-4,5-DIMETHANOL;(4S,5S)-2,2-DIMETHYL-ALPHA,ALPHA,ALPHA',ALPHA'-TETRA(2-NAPHTHYL)DIOXOLANE-4,5-DIMETHANOL;(+)-DINOL;(+)-2,3-O-isopropylidene-1,1,4,4-tetra (2-naph.)-D-threitol;(4S-trans)-2,2-di-me-A,A,A,A-tetra-2-nap -dioxo;(4S-TRANS)-2,2-DI-ME-A,A,A',A'-TETRA-2-N AP -DIOXOLAN-DIMETHANOL, 98%(99% EE/HPLC
CAS:137365-16-3
MF:C47H38O4
MW:666.8
EINECS:
Product Categories:
Mol File:137365-16-3.mol
(+)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-D-THREITOL Chemical Properties
Melting point 214-216 °C(lit.)
density 1.269±0.06 g/cm3(Predicted)
storage temp. 2-8°C
pka12.14±0.29(Predicted)
optical activity[α]20/D +116°, c = 1 in ethyl acetate
InChIKeyQWADMRIAKWGVBF-CXNSMIOJSA-N
Safety Information
WGK Germany 3
10
MSDS Information
ProviderLanguage
SigmaAldrich English
(+)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-D-THREITOL Usage And Synthesis
UsesReagent for the highly enantioselective addition of primary alkyl Grignards to ketones. Chiral auxiliary used for the asymmetric addition of nucleophiles to carbonyls.
(+)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-D-THREITOL Preparation Products And Raw materials

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