Product

(11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE

CAS No.：138517-66-5

Other grades of this product :

(11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE Basic information

Product Name:	(11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE
Synonyms:	(11S,12S)-11,12-diamino-9,10-dihydro-9,10-ethanoanthracene (R)-mandelate monoammonium salt;(11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE;(S,S)-11,12-Diamino-9,10-dihydro-9,10-ethanoanthracene;(11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine >=95.0% (HPLC);(11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine>9,10-Ethanoanthracene-11,12-diamine, 9,10-dihydro-, (11S,12S)-
CAS:	138517-66-5
MF:	C16H16N2
MW:	236.31
EINECS:
Product Categories:	Asymmetric Synthesis;Synthetic Organic Chemistry
Mol File:	138517-66-5.mol

(11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE Chemical Properties

Melting point	158 °C
Boiling point	396.7±42.0 °C(Predicted)
density	1.195±0.06 g/cm3(Predicted)
refractive index	20 ° (C=1, MeOH)
storage temp.	under inert gas (nitrogen or Argon) at 2–8 °C
form	powder to crystal
pka	9.38±0.40(Predicted)
color	White to Orange to Green
BRN	8693351

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26
WGK Germany	3

MSDS Information

(11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE Usage And Synthesis

Uses

(11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine is a chiral diamine, which can be used as a reactant:

To synthesize pyridine based C₂-symmetrical chiral organocatalysts via palladium catalyzed coupling reaction with 2-bromo-4-(alkylamino)pyridine.
To prepare porous organic imine cages by cycloimination reaction with triformylbenzene.
To synthesize Ga/Yb-Schiff base complex, which is utilized as a catalyst for the asymmetric synthesis of 5-amino-2-(hydroxyalkyl)oxazoles by enantioselective α-addition of α-isocyano amides to aldehydes.

(11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE Preparation Products And Raw materials

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