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| Chlorobis(ethylene)rhodium (I) dimer Basic information |
| Chlorobis(ethylene)rhodium (I) dimer Chemical Properties |
| storage temp. | -20°C | | solubility | Chloroform (Slightly, Heated, Sonicated), DMSO (Slightly, Heated, Sonicated), Me | | form | Crystalline Powder or Chunks | | color | Rust | | Water Solubility | Sparingly soluble in ethanol, acetone, dioxane, chloroform and dichloromethane. Insoluble in water. | | Sensitive | Air Sensitive | | Exposure limits | ACGIH: TWA 0.01 mg/m3; TWA 1 mg/m3NIOSH: IDLH 2 mg/m3; IDLH 100 mg/m3; TWA 0.001 mg/m3; TWA 0.1 mg/m3 | | Stability: | Air Sensitive | | InChIKey | OOQJCPOXJFCGCR-UHFFFAOYSA-L |
| Chlorobis(ethylene)rhodium (I) dimer Usage And Synthesis |
| Chemical Properties | red-brown powder | | Uses | Chlorobis(ethylene)rhodium(I) dimer is used as a precursor to rhodium(I) norbornadiene catalyst, which is used in an asymmetric 1,4-addition of arylboronic acids to cyclic enones. Further, it serves as an important organic intermediate. It catalyzes the dimerization of ethylene to 1-butene. It is also used in the preparation of homogeneous catalysts. | | Uses | Precursor to Rh(I) norbornadiene catalyst used in an asymmetric 1,4-addition of arylboronic acids to cyclic enones. |
| Chlorobis(ethylene)rhodium (I) dimer Preparation Products And Raw materials |
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