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| ETHYL 2 3-BUTADIENOATE 95 Basic information |
| ETHYL 2 3-BUTADIENOATE 95 Chemical Properties |
| Boiling point | 80 °C60 mm Hg(lit.) | | density | 0.966 g/mL at 25 °C(lit.) | | refractive index | n20/D 1.46(lit.) | | Fp | 116 °F | | storage temp. | <0°C | | form | clear liquid | | color | Colorless to Light yellow | | λmax | 209nm(MeOH)(lit.) |
| Risk Statements | 10 | | RIDADR | UN 1993 3/PG 2 | | WGK Germany | 3 | | HazardClass | 3 | | PackingGroup | III | | HS Code | 29161900 |
| ETHYL 2 3-BUTADIENOATE 95 Usage And Synthesis |
| Uses | Ethyl Buta-2,3-dienoate is a useful reactant for the synthesis of 9H-?pyrrolo[1,?2-?a]?indole derivatives via a phosphine-?promoted Michael addn.?/intramol. Wittig reaction. | | Uses | Ethyl 2,3-butadienoate may be used in the synthesis of dihydropyrans by reacting with acyclic enones. It may also be used to synthesize spiranic heterocycles by reacting with heterocyclic bis-arylidene ketones via phosphine-catalyzed [3+2] annulations. | | General Description | Ethyl 2,3-butadienoate is an α-allenic ester. The reaction of ethyl 2,3-butadienoate with N-tosylated imines in the presence of DABCO (1,4-diazabicyclo[2.2.2]octane) or DMAP (4-dimethylaminopyridine) forms azetidine derivatives or novel dihydropyridine derivatives respectively. The performance of bifunctional N-acyl aminophosphines to catalyze the asymmetric [3+2] cycloaddition of phenylidenemalononitrile with ethyl 2,3-butadienoate has been evaluated. |
| ETHYL 2 3-BUTADIENOATE 95 Preparation Products And Raw materials |
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