Allyl Benzyl Ether

Allyl Benzyl Ether
  • CAS No.:14593-43-2
Other grades of this product :
Allyl Benzyl Ether Basic information
Product Name:Allyl Benzyl Ether
Synonyms:alpha-(allyloxy)toluene;(Allyloxymethyl)benzene;[(Allyloxy)methyl]benzene;2-Propenyl benzyl ether;Benzyl 2-propenyl ether;Benzyl allyl ether;Ai3-07338;Benzene, ((2-propenyloxy)methyl)-
CAS:14593-43-2
MF:C10H12O
MW:148.2
EINECS:238-638-9
Product Categories:monomer;Allyl Monomers;Monomers;Polymer Science
Mol File:14593-43-2.mol
Allyl Benzyl Ether Chemical Properties
Boiling point 204-205 °C (lit.)
density 0.959 g/mL at 25 °C (lit.)
refractive index n20/D 1.507(lit.)
Fp 169 °F
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form clear liquid
color Colorless to Almost colorless
Specific Gravity0.96
EPA Substance Registry SystemBenzene, [(2-propenyloxy)methyl]- (14593-43-2)
Safety Information
Safety Statements 23-24/25
RIDADR NA 1993 / PGIII
WGK Germany 3
HS Code 2916310090
MSDS Information
ProviderLanguage
SigmaAldrich English
Allyl Benzyl Ether Usage And Synthesis
DescriptionBase polymer primarily from isobutylene with some 1- and 2-butene.
Chemical PropertiesColorless to Almost colorless clear liquid.
CharacteristicsLow odor, good heat stability, low color and broad compatibility with elastomers, plastics and tackifying resins.Does not readily oxidize. Contains no cyclic compounds.
PreparationBenzyl alcohol (108 mg, 1 mmol) was converted to allyl benzyl ether 11 in 96% yield in 4×5 h. IR (neat): 1630, 1090 cm–1 ; 1H NMR: d 7×34 (m, 5H), d 5×9–6×0 (m, 1H), d 5×17–5×35 (m, 2H), d 4×5 (s, 2H), d 4×04 (d, J = 1×46 Hz, 2H).
ApplicationBase polymer in hot melt adhesives and paper-laminating, extender and viscosity modifier in caulks and sealants and waterproofing agent in wire and cable applications.Cosmetic additive, metal working lubricant, polymer lubricant and modifier for tire sealants.
Synthesis Reference(s)Tetrahedron Letters, 35, p. 4367, 1994 DOI: 10.1016/S0040-4039(00)73357-0
Allyl Benzyl Ether Preparation Products And Raw materials
Preparation ProductsBENZYL PROPARGYL ETHER-->ALLYL BENZOATE-->methyl 2-(benzyloxy)acetate-->2-Allylcyclohexanone-->BENZYL GLYCIDYL ETHER

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