(R)-VAPOL

(R)-VAPOL
  • CAS No.:147702-16-7
Other grades of this product :
(R)-VAPOL Basic information
Reaction
Product Name:(R)-VAPOL
Synonyms:(R)-VAPOL 97%;(R)-VAPOL,99%e.e.;(S)-2,2'-DIPHENYL-(4-BIPHENANTHROL);(R)-VAPOL;(S)-VAPOL;(R)-2,2'-DIPHENYL-3,3'-(4-BIPHENANTHROL);(3R)-(-)-2,2'-DIPHENYL-[3,3'-BIPHENANTHRENE]-4,4'-DIOL DICHLOROMETHANE ADDUCT;(3S)-(+)-2,2'-DIPHENYL-[3,3'-BIPHENANTHRENE]-4,4'-DIOL DICHLOROMETHANE ADDUCT
CAS:147702-16-7
MF:C40H26O2
MW:538.63
EINECS:
Product Categories:BINOL Series;Chiral Oxygen
Mol File:147702-16-7.mol
(R)-VAPOL Chemical Properties
Melting point 225-229 °C
alpha -123.4° (c 1.0, THF)
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
form Powder
color white to pale yellow
optical activity[α]20/D -144°, c = 1 in chloroform
Safety Information
Hazard Codes Xn
Risk Statements 37/38-40-41
Safety Statements 26-36/37/39
WGK Germany 3
MSDS Information
(R)-VAPOL Usage And Synthesis
Reaction
  1. Chiral ligand used in catalytic asymmetric aziridination.
  2. Chiral ligand used in catalytic asymmetric imino aldol reaction.
  3. Chiral ligand used in catalytic asymmetric Petasis reaction. 
UsesVAPOL has proven to be an excellent ligand in catalytic asymmetric Diels-Alder, imine aldol, and aziridination reactions.
(R)-VAPOL Preparation Products And Raw materials

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