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| 2-CHLOROPHENYLZINC IODIDE Basic information |
| Product Name: | 2-CHLOROPHENYLZINC IODIDE | | Synonyms: | 2-CHLOROPHENYLZINC IODIDE;2-CHLOROPHENYLZINC IODIDE, 0.5M SOLUTION IN TETRAHYDROFURAN;2-chlorophenylzinc iodide solution;2-Chlorophenylzinc iodide solution 0.5 in THF;2-Chlorophenylzinc iodide, Packaged under Argon in resealable ChemSeal? bottles;2-Chlorophenylzinc iodide solution 0.5M in THF;2-Chlorophenylzinc iodide 0.5 M in Tetrahydrofuran;2-Chlorophenylzinc iodide, 0.5M in THF, packaged under Argon in resealable CheMSeal^t bottles | | CAS: | 148651-35-8 | | MF: | C6H4ClIZn | | MW: | 303.84 | | EINECS: | | Product Categories: | Aryl;Organozinc Halides;Reike and Organozinc Reagents | | Mol File: | 148651-35-8.mol |
| 2-CHLOROPHENYLZINC IODIDE Chemical Properties |
| density | 0.973 g/mL at 25 °C | | Fp | 1 °F | | storage temp. | 2-8°C | | Sensitive | Air & Light Sensitive | | Exposure limits | ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)OSHA: TWA 200 ppm(590 mg/m3)NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3) | | CAS DataBase Reference | 148651-35-8 |
| 2-CHLOROPHENYLZINC IODIDE Usage And Synthesis |
| Uses | 2-Chlorophenylzinc iodide is an organozinc compound, which can be used as a reactant in Negishi cross-coupling reaction to construct carbon-carbon bonds by reacting with organic halides using nickel or palladium catalysts. It can also be utilized as a reactant to prepare: - Arylmethanes via rhodium-catalyzed cross-coupling reaction with methyl halides.
- (2-chlorobenzyl)trimethylsilane by Rh-catalyzed cross-coupling reaction with (iodomethyl)trimethylsilane.
- Dichloro biphenyl by palladium catalyzed oxidative homocoupling reaction using N-chlorosuccinimide (NCS) or O2 as the oxidant.
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| 2-CHLOROPHENYLZINC IODIDE Preparation Products And Raw materials |
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