(R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE

CAS No.：149341-33-3

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This product is a chemical product/pharmaceutical intermediate. It is not a drug, an active pharmaceutical ingredient (API), or a pharmaceutical-grade material. It has not been granted a drug approval number or a Chemical Drug Substance Approval Notice, has not passed drug-related review and approval, and is not manufactured, tested, or released in accordance with pharmaceutical GMP.
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(R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE Basic information

Product Name:	(R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE
Synonyms:	(S)-QUINAP;(R)-QUINAP;R-QUINAR;(S)-(-)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE;(S)-(-)-1-(2-Diphenylphosphino-1-naphthyl)isoquinoline S-QUINAP;(S)-(-)-1-(2-Diphenylphosphino-1-naphthyl)isoquinoline,98%;(S)-(-)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE;(R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE;(S)-(-)-1-(2-Diphenylphosphino-1-naphthyl)isoquinoline >=95.0% (qNMR)
CAS:	149341-33-3
MF:	C31H22NP
MW:	439.49
EINECS:
Product Categories:	organophosphine ligand
Mol File:	149341-33-3.mol

(R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE Chemical Properties

Melting point	220-230 °C
Boiling point	588.1±38.0 °C(Predicted)
storage temp.	2-8°C
pka	4.45±0.30(Predicted)
form	Crystalline Powder
color	White to off-white
BRN	6664856

Safety Information

Hazard Codes	Xi,Xn
Risk Statements	36/37/38-22
Safety Statements	37/39-26
WGK Germany	3
HS Code	29334990

MSDS Information

Provider	Language
ACROS	English

(R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE Usage And Synthesis

Chemical Properties	white to off-white crystalline powder
Uses	(S)-QUINAP can be used as a ligand: In the asymmetric hydrosilylation of alkyl and α, β-unsaturated ketones in the presence of Fe(OAc)₂.?????? For the synthesis of chiral organoboron compounds by copper-catalyzed β-borylation of α,β-unsaturated esters. [Ir(cod)Cl]₂ treated with ligand (S)-QUINAP forms an iridium complex. This complex is used as a catalyst for the enantioselective hydrogenation of olefins. (S)-QUINAP–Rh complex can be employed as a catalyst in enantioselective hydroboration/oxidation of perfluoroalkenes.
General Description	(S)-QUINAP is a bidentate ligand used in catalytic asymmetric hydroboration, hydrogenation, oxidation, and allylic alkylation reactions.

(R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE Preparation Products And Raw materials

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