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| 3-METHYLOXINDOLE 96 Basic information |
| 3-METHYLOXINDOLE 96 Chemical Properties |
| Melting point | 117-121 °C(lit.) | | Boiling point | 279.3±29.0 °C(Predicted) | | density | 1.123±0.06 g/cm3(Predicted) | | storage temp. | Sealed in dry,Room Temperature | | pka | 14.81±0.40(Predicted) | | Water Solubility | Insoluble in water. | | CAS DataBase Reference | 1504-06-9 |
| WGK Germany | 3 | | HS Code | 2933790090 |
| 3-METHYLOXINDOLE 96 Usage And Synthesis |
| Uses | 3-Methylindole metabolite. | | Uses | • ;Reactant for enantioselective α-amination reactions1• ;Reactant for aldol reaction with glyoxal derivatives2• ;Reactant for amine thiourea catalyzed conjugate addition to α,β-unsaturated aldehydes3• ;Reactant for O-acetylation reactions4• ;Reactant for preparation of a disubstituted oxoindole by using rhodium-catalyzed cyclopropanation/ring-opening reactions5 | | Uses | A versatile reactant. As 3-Methylindole metabolite. Reactant for enantioselective α-amination reactions, Reactant for aldol reaction with glyoxal derivatives, Reactant for amine thiourea catalyzed conjugate addition to α,β-unsaturated aldehydes, Reactant for O-acetylation reactions, Reactant for preparation of a disubstituted oxoindole by using rhodium-catalyzed cyclopropanation/ring-opening reactions. | | General Description | 3-Methyl-2-oxindole (MOI) is a 3-substituted-2-oxindole. It is reported to be formed during the oxidation of indole-3-acetic acid in the presence of FeII under aerobic conditions. MOI undergoes asymmetric anti-Mannich-type reaction with N-tosyl aryl aldimines in the presence of alkaloid cinchona derivatives to form anti-3,3-disubsituted 2-oxindole derivatives. It also undergoes asymmetric hydroxyamination with nitrosoarenes to form N-nitroso aldol products. |
| 3-METHYLOXINDOLE 96 Preparation Products And Raw materials |
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