(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE

(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE
  • CAS No.:1517-82-4
Other grades of this product :
(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE Basic information
Product Name:(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE
Synonyms:(S)-(-)-Menthyl p-toluenesulfinate, (-)-(1R)-Menthyl (S)-p-toluenesulfinate;4-Methylbenzenesulfinic acid (1R)-2α-isopropyl-5β-methylcyclohexane-1β-yl ester;4-Methylbenzenesulfinic acid (1R,3R,4S)-p-menthane-3-yl ester;p-Toluenesulfinic acid (1R,1β)-2α-isopropyl-5β-methylcyclohexyl ester;p-Toluenesulfinic acid (1R,2S,5R)-2-isopropyl-5-methylcyclohexyl ester;p-Toluenesulfinic acid (1R,3R,4S)-menthyl ester;p-Toluenesulfinic acid (1R,3R,4S)-p-menthane-3-yl ester;(1R,2S,5R)-(-)-Menthyl (S)-p-toluenesulfinate,98%
CAS:1517-82-4
MF:C17H26O2S
MW:294.45
EINECS:
Product Categories:Chiral Building Blocks;Organic Building Blocks;chiral;Asymmetric Synthesis;Biochemistry;Sulfonates/Sulfinates;Monocyclic Monoterpenes;Synthetic Organic Chemistry;Terpenes
Mol File:1517-82-4.mol
(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE Chemical Properties
Melting point 99-104 °C
Boiling point 402.3±38.0 °C(Predicted)
density 1.08
refractive index -199 ° (C=1.5, Acetone)
storage temp. -20°C
solubility Acetone (Slightly), Chloroform (Slightly)
form Solution
color Yellow to brown or gray
optical activity[α]20/D 195°, c = 2 in acetone
BRN 3207468
Safety Information
Safety Statements 22-24/25
WGK Germany 3
HS Code 29309090
MSDS Information
ProviderLanguage
SigmaAldrich English
(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE Usage And Synthesis
Chemical PropertiesWhite crystalline powder
Uses(1R,2S,5R)-(-)-Menthyl (S)-p-Toluenesulfinate is a reactant used in the synthesis of sulfoxide pincer complexes of Mg, Rh and Ir.
Uses(1R,2S,5R)-(-)-Menthyl (S)-p-toluenesulfinate can react with:
  • metal ketimines to form enantiopure sulfinimines
  • p-(methylthio)benzaldehyde to form (S)-(-)-N-(4-methylthiobenzylidene)-p-toluenesulfinimine
General Description(1R,2S,5R)-(-)-Menthyl (S)-p-toluenesulfinate is mainly used for the introduction of p-toluenesulfinyl group in asymmetric synthesis.

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