RANEY NICKEL

RANEY NICKEL
  • CAS No.:12635-27-7
Other grades of this product :
RANEY NICKEL Basic information
Product Name:RANEY NICKEL
Synonyms:Nickel-aluminium alloy~Raney(rg nickel alloy;nickel-aluminum alloy 50% ni + 50% al;Aluminium-nickel alloy, 50/50 Al/Ni;Nickel-aluminum alloy, Raney(R)-Nickel alloy;Nickel-aluminium alloy (50:50), powder;Raney\(rgnickelalloy;Aluminum alloy, base, Al 50,Ni 50;SKELETAL NICKEL CATALYST
CAS:12635-27-7
MF:AlNi
MW:85.67
EINECS:682-897-4
Product Categories:Catalysis and Inorganic Chemistry;Chemical Synthesis
Mol File:12635-27-7.mol
RANEY NICKEL Chemical Properties
density 3.46 g/mL at 25 °C(lit.)
form slurry
color Gray to black
Water Solubility Insoluble in water.
Safety Information
Hazard Codes F,Xn
Risk Statements 17-40-43-15
Safety Statements 5-15-22-36-43-36/37
RIDADR UN 3089 4.1/PG 2
WGK Germany 3
TSCA Yes
HazardClass 4.3
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
RANEY NICKEL Usage And Synthesis
UsesNickel aluminides, Ni3Al, NiAl: The intermetallic phase Ni3Al is the well known Y phase which is as coherent fcc precipitate responsible for the good creep properties of nickel base superalloys. Ni3Al and NiAl were also considered for high temperature structural applications mainly in the 1990-ies. Powder metallurgical as well as melt metallurgical production were pursued. High production cost, lacking low temperature ductility and lacking microstructural stability were responsible that there was never a real break-through of these materials for structural applications.
UsesAluminum-nickel alloy can be used:
  • For the reduction of nitriles, nitro compounds and oximes to primary amines.
  • For the conversion of carbonyl compounds to hydrocarbons.
  • As a reducing agent to convert Ar-X derivatives to Ar-H compounds.
  • For the synthesis of Raney nickel catalyst to be used as an alkylating agent.
  • To synthesize non-pyrophoric Ni catalyst by alkali leaching.
  • For the synthesis of alloyed skeletal Ni catalysts.

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