(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE

CAS No.：164931-83-3

Other grades of this product :

(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE Basic information

Reactions

Product Name:	(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE
Synonyms:	(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE;（1R,2R）-(－)-〔1，2-Cyclohexanediamino-N,N-bis(3,5-di-t-butylsalicylidene)〕chromium(Ⅲ) Chloride;(1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-tert-butylsalicylidene)]chromium(III)chloride;(r,r)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(iii) chloride;(r,r)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexan;Chromium,chloro[[2,2'-[(1R,2R)-1,2-cyclohexanediylbis[(nitrilo-kN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-kO]](2-)]-, (SP-5-13)-;(R,R)Jacbosen;RR,R)-N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(III)chloride
CAS:	164931-83-3
MF:	C36H52ClCrN2O2
MW:	632.27
EINECS:	605-379-1
Product Categories:	Asymmetric Synthesis;Chiral Catalysts, Ligands, and Reagents;CycloadditionChiral Catalysts, Ligands, and Reagents;Privileged Ligands and Complexes;SALENs
Mol File:	164931-83-3.mol

(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE Chemical Properties

Melting point	>350 °C(lit.)
form	Powder
color	brown

Safety Information

Hazard Codes	Xn
Risk Statements	20/21/22
Safety Statements	26-36
WGK Germany	3

MSDS Information

(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE Usage And Synthesis

Reactions

Catalyst for the asymmetric ring-opening of meso-epoxides and for the kinetic resolution of terminal epoxides.
Precatalyst for asymmetric Diels-Alder and hetero Diels-Alder reactions.
Catalyst for copolymerization of CO2 and epoxides.
Catalyst for enantioselective alkylation of tributyltin enolates.
Enantioselective addition of Me2Zn to aldehydes.
Enantioselective intramolecular addition of tertiary enamides to ketones.
Asymmetric iodocyclization.
Catalytic intermolecular linear allylic C-H animation.

Uses

Catalyst used for:

Asymmetric anti-Mannich reactions
Coupling reactions
Ring-opening and Diels-Alder reactions
Allylic C-H oxidation of terminal alkenes

(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE Preparation Products And Raw materials

Welcome！

Please leave a message for us or use the following ways to contact us, we will reply to you as soon as possible, and provide you with the most sincere service, thank you.

NO. 18 ,Wujiang Road, Wulidian Street, Jiangbei District, Chongqing
+86-23-6139-8061 +86-13650506873
danny@chemdad.com sales@chemdad.com
www.chemdad.com
WhatsApp +86-13650506873