(1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL

CAS No.：16854-32-3

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(1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL Basic information

Product Name:	(1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL
Synonyms:	2-Amino-1-[4-(methylthio)phenyl]-1,3-propanediol;[S(R,R)]-2-amino-1-[p-(methylthio)phenyl]propane-1,3-diol;L-THIOMICAMINE;(1S,2S)-(+)-THIOMICAMINE;(1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL;thiomicamine;(1S,2S)-1-[4-(Methylthio)phenyl]-2-amino-1,3-propanediol;(1S,2S)-1-[4-(Methylthio)phenyl]-2-aminopropane-1,3-diol
CAS:	16854-32-3
MF:	C10H15NO2S
MW:	213.3
EINECS:	240-878-4
Product Categories:
Mol File:	16854-32-3.mol

(1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL Chemical Properties

Melting point	151-154 °C(lit.)
Boiling point	428.2±45.0 °C(Predicted)
density	1.25±0.1 g/cm3(Predicted)
pka	11.75±0.45(Predicted)
optical activity	[α]25/D +25°, c = 1 in ethanol
CAS DataBase Reference	16854-32-3(CAS DataBase Reference)

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-37/39
WGK Germany	3
HS Code	2930909899

MSDS Information

Provider	Language
SigmaAldrich	English

(1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL Usage And Synthesis

Uses

(1S,2S)-(+)-Thiomicamine can be used:

As a starting material in the synthesis of 3,4-dihydroisoquinolinium salts, which are employed as promoters in asymmetric epoxidation and oxidation?reactions.
As a starting material in the synthesis of an α-amino acid named (3R,4R)-4-phenyl-1,2,3,4-tetrahydroisoquinoline-3-carboxylic acid, which is used to prepare modified peptides of biological importance.
As a chiral base in the resolution of an angiotensin II type 2 receptor [AT₂R] antagonist named EMA401.

(1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL Preparation Products And Raw materials

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