1,3-Dimesitylimidazolidin-2-ylidene

1,3-Dimesitylimidazolidin-2-ylidene
  • CAS No.:173035-11-5
Other grades of this product :
1,3-Dimesitylimidazolidin-2-ylidene Basic information
Reactions
Product Name:1,3-Dimesitylimidazolidin-2-ylidene
Synonyms:1,3-Dimesitylimidazolidin-2-ylidene;1,3-Bis(2,4,6-trimethylphenyl)-4,5- dihydroimidazol-2-ylidene, min. 98%;1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene;1,3-Bis(2,4,6-trimethyphenyl)4,5- dihydroimidazol-2-ylidene;1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydro-2H-imidazol-1-ium-2-ide;1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene ;IMesH2;SIMes
CAS:173035-11-5
MF:C21H26N2
MW:306.45
EINECS:
Product Categories:N-heterocyclic carbene
Mol File:173035-11-5.mol
1,3-Dimesitylimidazolidin-2-ylidene Chemical Properties
Melting point 85-100°C
storage temp. -20°C
form Powder
color pale yellow
Sensitive air sensitive, moisture sensitive
Safety Information
WGK Germany 3
MSDS Information
1,3-Dimesitylimidazolidin-2-ylidene Usage And Synthesis
Reactions
  1. Ligand for copper-catalyzed regioselective formation of tri- and tetrasubstituted vinylboronates in air.
  2. Ligand for highly active ruthenium catalyst for hydrogenation of olefins.
  3. Electrophilic phosphonium cations component for ketone catalytic hydrodeoxygenation/hydrosilylation.
  4. Used in selective activation of fluoroalkenes to produce N-heterocyclic fluoroalkenes and polyfluoroalkenyl imidazolium salts.
1,3-Dimesitylimidazolidin-2-ylidene Preparation Products And Raw materials
Raw materials1,3-Bis(2,4,6-trimethylphenyl)-2-(trichloromethyl)imidazolidine-->1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE

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