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| Cyanomethylenetrimethylphosphorane solution Basic information |
| Product Name: | Cyanomethylenetrimethylphosphorane solution | | Synonyms: | (Trimethylphosphoranylidene)acetonitrile solution;(Trimethylphosphoranylidene)acetonitrile;Cyanomethylenetrimethylphosphorane solution;(Trimethylphosphoranylidene)acetonitrile solution 0.5 M in THF;2-(trimethyl-$l^{5}-phosphanylidene)acetonitrile;Acetonitrile, 2-(trimethylphosphoranylidene)- | | CAS: | 176325-83-0 | | MF: | C5H10NP | | MW: | 115.11 | | EINECS: | | Product Categories: | | Mol File: | 176325-83-0.mol |
| Cyanomethylenetrimethylphosphorane solution Chemical Properties |
| density | 0.896 g/mL at 25 °C | | Fp | -21℃ | | storage temp. | 2-8°C |
| Cyanomethylenetrimethylphosphorane solution Usage And Synthesis |
| General Description | (Trimethylphosphoranylidene)acetonitrile is a reagent generally employed in the Wittig olefination of less reactive carboxylic acid compounds like esters, N-Boc lactams, lactones, and imides to give α,β-unsaturated nitriles. It is also used as an alternate reagent for Mitsonobu reaction by replacing DEAD/PPh3 for the alkylation of C-H and N-H bonds. |
| Cyanomethylenetrimethylphosphorane solution Preparation Products And Raw materials |
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