METHYL 2-BROMO-2-BUTENOATE

METHYL 2-BROMO-2-BUTENOATE
  • CAS No.:17642-18-1
Other grades of this product :
METHYL 2-BROMO-2-BUTENOATE Basic information
Product Name:METHYL 2-BROMO-2-BUTENOATE
Synonyms:METHYL 2-BROMO-2-BUTENOATE;METHYL 2-BROMOCROTONATE;METHYL A-BROMOCROTONATE;methyl 2-bromo-2-butenoate (cis+trans);2-Bromo-2-butenoic acid methyl ester;Einecs 241-627-1;(Z)-Methyl 2-broMobut-2-enoate;Methyl 2-bromo-2-butenoate (cis+trans), >=95.0% (GC)
CAS:17642-18-1
MF:C5H7BrO2
MW:179.01
EINECS:241-627-1
Product Categories:
Mol File:17642-18-1.mol
METHYL 2-BROMO-2-BUTENOATE Chemical Properties
Boiling point 178-182 °C (lit.)
density 1.505 g/mL at 20 °C (lit.)
refractive index n20/D 1.486
Fp 63 °C
storage temp. 2-8°C
BRN 1700999
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
8
MSDS Information
ProviderLanguage
SigmaAldrich English
METHYL 2-BROMO-2-BUTENOATE Usage And Synthesis
General DescriptionMethyl 2-bromo-2-butenoate(Methyl (Z)-2-bromocrotonate) yields (S)-2-bromobutanoic acid by baker′s yeast fermentation. It undergoes biotransformation catalyzed by old yellow enzyme to yield methyl (S)-2-bromobutanoate, a key intermediate for the synthesis of chiral drugs. It is a biannelating reagent which participates in double Michael-additions.
METHYL 2-BROMO-2-BUTENOATE Preparation Products And Raw materials

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