DIFORMYLIMIDE SODIUM SALT

DIFORMYLIMIDE SODIUM SALT
  • CAS No.:18197-26-7
Other grades of this product :
DIFORMYLIMIDE SODIUM SALT Basic information
Product Name:DIFORMYLIMIDE SODIUM SALT
Synonyms:SodiuM diforMaMide, 98% 5GR;N-ForMylforMaMide, sodiuM salt;Formamide, N-formyl-,sodium salt (9CI);sodium,diformylazanide;DIFORMYLAMIDE SODIUM SALT;DIFORMYLIMIDE SODIUM SALT;SODIUM DIFORMAMIDE;SODIUM DIFORMYLAMIDE
CAS:18197-26-7
MF:C2H2NNaO2
MW:95.03255
EINECS:
Product Categories:Amination;Classes of Metal Compounds;Na (Sodium) Compounds (excluding simple sodium salts);Synthetic Organic Chemistry;Typical Metal Compounds;CHIRAL CHEMICALS
Mol File:18197-26-7.mol
DIFORMYLIMIDE SODIUM SALT Chemical Properties
Melting point 205°C
Fp 78.9℃
storage temp. Inert atmosphere,2-8°C
Water Solubility Soluble in water
form Powder
color Slightly beige
BRN 3567185
CAS DataBase Reference18197-26-7(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
3-9-34
HS Code 29251900
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
DIFORMYLIMIDE SODIUM SALT Usage And Synthesis
Chemical PropertiesSlightly beige powder
UsesReactant for preparation of:
  • Functionalized condensed benzazoles
  • α-ketoheterocycles as inhibitors of Leishmania mexicana cysteine protease CPB
  • INOS inhibitor PHA-399733 via Bucherer-Bergs hydantoin synthesis
  • Antibiotic resistance (C β-lactamase AmpC ) inhibitor analogues, with improved cell permeability properties
  • BINOL- and H8-BINOL-based aryl phosphites as ligands in palladium-catalyzed asymmetric allylation and amination reactions
  • Precursors of αVβ3 integrin antagonists
Purification MethodsGrind the amide under dry tetrahydrofuran (fumehood), filter and wash it with this solvent, then dry it in vacuo. It is soluble in EtOH and H2O but insoluble in Et2O and pet ether. [IR and preparation: Rakshit J Chem Soc 103 1557 1913, Yinglin & Hongwen Synthesis 122 1990, Allenstein & Beyl Chem Ber 100 355 1967, Allenstein et al. Chem Ber 102 4089 1969, Beilstein 2 II 22.]
DIFORMYLIMIDE SODIUM SALT Preparation Products And Raw materials
Preparation Products2-AMINO-4'-CHLOROACETOPHENONE HYDROCHLORIDE

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