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| 5-ISOPROPYL-1,3-CYCLOHEXANEDIONE Basic information |
| 5-ISOPROPYL-1,3-CYCLOHEXANEDIONE Chemical Properties |
| Melting point | 63-65 °C (lit.) | | CAS DataBase Reference | 18456-87-6 |
| Hazard Codes | Xi | | Risk Statements | 43 | | Safety Statements | 36/37 | | WGK Germany | 3 | | HS Code | 2914290090 |
| 5-ISOPROPYL-1,3-CYCLOHEXANEDIONE Usage And Synthesis |
| Uses | 5-Isopropyl-1,3-cyclohexanedione may be used as starting reagent for the synthesis of carvotanacetone analogs. It may be used in the preparation of monocyclic terepenes. It may be used in the synthesis of 2H-pyrans, via reaction with α,β-unsaturated aldehydes. | | Synthesis Reference(s) | Journal of the American Chemical Society, 72, p. 1645, 1950 DOI: 10.1021/ja01160a060 | | General Description | 5-Isopropyl-1,3-cyclohexanedione is a cyclic 1,3-diketone. It can be prepared by condensation of isobutylideneacetone with ethyl malonate. 5-Isopropyl-1,3-cyclohexanedione on methylation with methyl iodide yields 5-isopropyl-2-methyl-1,3-cyclohexanedione. A multistep-synthesis of 5-isopropyl-1,3-cyclohexanedione involving aldol condensation, Dieckmann-type annulation, ester hydrolysis and decarboxylation is reported. |
| 5-ISOPROPYL-1,3-CYCLOHEXANEDIONE Preparation Products And Raw materials |
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