Mes-Umemoto reagent

Mes-Umemoto reagent
  • CAS No.:1895006-01-5
Other grades of this product :
Mes-Umemoto reagent Basic information
Product Name:Mes-Umemoto reagent
Synonyms:Mes-Umemoto reagent;dimesityl(trifluoromethyl)sulfonium trifluoromethanesulfonate;Mes-Umemoto reagent >=95%;Dimesityl(trifluoromethyl)sulfonium Triflate
CAS:1895006-01-5
MF:C20H22F6O3S2
MW:488.5
EINECS:
Product Categories:
Mol File:1895006-01-5.mol
Mes-Umemoto reagent Chemical Properties
storage temp. -20°C
Safety Information
MSDS Information
Mes-Umemoto reagent Usage And Synthesis
UsesUnder a dual catalytic copper/photoredox manifold, the Mes-Umemoto reagent has been demonstrated by the MacMillan lab to be an excellent reagent for the trifluoromethylation of alkyl halides and aryl halides to yield alkyl-CF3 and aryl-CF3 in high yields. In both cases, these reactions exhibit wide substrate scope with good functional group tolerance. More specifically, a variety of 5-membered and 6-membered heteroaryl halides can be readily converted to the corresponding trifluoromethylheteroarenes under mild conditions. To be use in conjunction with supersilanol (902489) and Ir photocatalyst (902217 or 902225).
Mes-Umemoto reagent Preparation Products And Raw materials

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