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| Mes-Umemoto reagent Basic information |
| Product Name: | Mes-Umemoto reagent | | Synonyms: | Mes-Umemoto reagent;dimesityl(trifluoromethyl)sulfonium trifluoromethanesulfonate;Mes-Umemoto reagent >=95%;Dimesityl(trifluoromethyl)sulfonium Triflate | | CAS: | 1895006-01-5 | | MF: | C20H22F6O3S2 | | MW: | 488.5 | | EINECS: | | Product Categories: | | Mol File: | 1895006-01-5.mol |
| Mes-Umemoto reagent Chemical Properties |
| Mes-Umemoto reagent Usage And Synthesis |
| Uses | Under a dual catalytic copper/photoredox manifold, the Mes-Umemoto reagent has been demonstrated by the MacMillan lab to be an excellent reagent for the trifluoromethylation of alkyl halides and aryl halides to yield alkyl-CF3 and aryl-CF3 in high yields. In both cases, these reactions exhibit wide substrate scope with good functional group tolerance. More specifically, a variety of 5-membered and 6-membered heteroaryl halides can be readily converted to the corresponding trifluoromethylheteroarenes under mild conditions. To be use in conjunction with supersilanol (902489) and Ir photocatalyst (902217 or 902225). |
| Mes-Umemoto reagent Preparation Products And Raw materials |
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