(S)-(-)-N,ALPHA-DIMETHYLBENZYLAMINE

(S)-(-)-N,ALPHA-DIMETHYLBENZYLAMINE
  • CAS No.:19131-99-8
Other grades of this product :
(S)-(-)-N,ALPHA-DIMETHYLBENZYLAMINE Basic information
Product Name:(S)-(-)-N,ALPHA-DIMETHYLBENZYLAMINE
Synonyms:(S)-N-METHYL-1-PHENYLETHANAMINE;S(-)-N-METHYL-1-PHENYLETHYLAMINE;(S)(-)-N-METHYL-ALPHA-PHENETHYLAMINE;(S)-N-METHYL-ALPHA-PHENYLETHYLAMINE;(S)-(-)-N-METHYL A-METHYLBENZYLAMINE;(S)-(-)-N,ALPHA-DIMETHYLBENZYLAMINE;(1S)-N-Methyl-1-phenylethanamine;(S)-(-0-N,α-DIMETHYLBENZYLAMINE
CAS:19131-99-8
MF:C9H13N
MW:135.21
EINECS:
Product Categories:Chiral Compound
Mol File:19131-99-8.mol
(S)-(-)-N,ALPHA-DIMETHYLBENZYLAMINE Chemical Properties
Melting point 116°C (estimate)
alpha -72o (C=2 IN CHLOROFORM)
Boiling point 74-76 °C11 mm Hg(lit.)
density 0.928 g/mL at 20 °C(lit.)
refractive index n20/D 1.512(lit.)
Fp 143 °F
storage temp. Keep in dark place,Inert atmosphere,Room temperature
pka9.77±0.10(Predicted)
form clear liquid
color Colorless to Almost colorless
optical activity[α]20/D 73±5°, c = 2 in chloroform
BRN 1446867
Safety Information
Hazard Codes C
Risk Statements 20/21/22-34
Safety Statements 26-36-45
RIDADR UN 2619 8/PG 2
WGK Germany 3
10-23
HazardClass IRRITANT
HS Code 29214990
MSDS Information
ProviderLanguage
SigmaAldrich English
(S)-(-)-N,ALPHA-DIMETHYLBENZYLAMINE Usage And Synthesis
UsesUsed to make asymmetric organometallic catalysts (e.g., for conjugate additions to enones).
General Description(S)-(-)-N,a-Dimethylbenzylamine may be used along with benzaldehyde in the Mannich-type aminoalkylation of 2-naphthol to form 1-((S)-phenyl(((1′S)-1′-phenylethyl)methylamino)methyl)-2-naphthol. This optically active tertiary aminonaphthol can catalyze the enantioselective alkenylation of various aldehyde to generate chiral (E)- allyl alcohols.

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